HEXAMETHYL-D18-DISILOXANE

Base Information

• Chemical Name: HEXAMETHYL-D18-DISILOXANE
• CAS No.: 19108-55-5
• Molecular Formula: C6D18 O Si2
• Molecular Weight: 180.236
• Mol file: 19108-55-5.mol

Synonyms:HEXAMETHYL-D18-DISILOXANE

Chemical Property of HEXAMETHYL-D18-DISILOXANE

Chemical Property:

• PSA: 9.23000
• LogP: 2.67280

Purity/Quality:

98% ^*data from raw suppliers

Hexamethyl-d18-disiloxane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Hexamethyl-d18-disiloxane (CAS# 19108-55-5) is a useful isotopically labeled research compound.

Technology Process of HEXAMETHYL-D18-DISILOXANE

There total 2 articles about HEXAMETHYL-D18-DISILOXANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro-trimethyl-silane (75-77-4) + C38H40(2)H18MoO2P2Si2 → <2H18>Hexamethyldisiloxane (19108-55-5) + C35H49ClMoOP2Si + hexamethyldisiloxane-d9 (127663-93-8)

Guidance literature:

In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/jacs.6b10535

Reference yield:

→ <2H18>Hexamethyldisiloxane (19108-55-5)

Guidance literature:

(CD3)3SiCl, Hydrolyse;

Reference yield:

<2H18>Hexamethyldisiloxane (19108-55-5) → formic acid (64-18-6) + C5H(2)H15O2Si2 + C6(2)H16O3Si2

Guidance literature:

With air; chlorine; n-butane; at 22.9 ℃; under 740 Torr; Rate constant; Irradiation;

DOI:10.1039/ft9959103033

upstream raw materials:

chloro-trimethyl-silane

Downstream raw materials:

formic acid

Refernces