1-(Chloromethyl)-o-carborane

Base Information

Chemical Name:1-(Chloromethyl)-o-carborane
CAS No.:17786-07-1
Molecular Formula:C3H13 B10 Cl
Molecular Weight:192.699
Hs Code.:

Synonyms:1-(Chloromethyl)-1,2-carbadodecaborane(12);1-(Chloromethyl)-o-carborane

Suppliers and Price of 1-(Chloromethyl)-o-carborane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 1-(Chloromethyl)-o-carborane

Chemical Property:

PSA：0.00000
LogP:-5.46740

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1-(Chloromethyl)-o-carborane

There total 2 articles about 1-(Chloromethyl)-o-carborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 7719-09-7
thionyl chloride

: 19610-34-5
(1'-hydroxymethyl)-1,2-dicarba-closo-dodecaborane

: 17786-07-1
1-(CH₂Cl)-1,2-C₂HB₁₀H₁₀

Guidance literature:: In chloroform; addn. of soln. of SOCl2 in CHCl3 at -20 °C to soln. of 1-CH2OH-1.2-C2B10H11 in CHCl3 (contg. pyridine), addn. of H2O after 20 h at room temp.;; isolation from org. phase by sublimation in vac. after removing solvent;;

Reference yield: 25.8%

: 19610-34-5
(1'-hydroxymethyl)-1,2-dicarba-closo-dodecaborane

: 10026-13-8,874483-75-7
phosphorus pentachloride

: 17786-07-1
1-(CH₂Cl)-1,2-C₂HB₁₀H₁₀

: 83608-53-1
tris(o-carboranylmethyl) phosphate

Guidance literature:: In benzene; addn. of carborane to soln. of PCl5 (stirring, 20°C), boiling (4h); removal of solvent (distn. off), column chromy. (silica gel, hexane, benzene); elem. anal, GLC anal.;
DOI:10.1007/BF00954165

Reference yield:

: 17786-07-1
1-(CH₂Cl)-1,2-C₂HB₁₀H₁₀

: 7439-95-4
magnesium

: 16872-10-9
1-methyl-o-carborane

: 219864-16-1
1,2-dicarba-closo-dodecaboran-1-yl-methyl-MgCl

: 66035-59-4
1-CH₃-2-MgCl-1.2-C₂B₁₀H₁₀

: 1-CH₂MgCl-2-MgCl-1.2-C₂B₁₀H₁₀

Guidance literature:: In diethyl ether; Grignard-react. in diethyl ether;;
DOI:10.1021/ic50010a008 DOI:10.1021/ic50010a009 DOI:10.1021/ic50010a004