Nitrosonium hexafluoroantimonate

Base Information

• Chemical Name: Nitrosonium hexafluoroantimonate
• CAS No.: 16941-06-3
• Molecular Formula: F6NOSb
• Molecular Weight: 265.747
• Hs Code.: 2826908090
• European Community (EC) Number: 626-847-1
• DSSTox Substance ID: DTXSID00587321
• Wikidata: Q61778901
• Mol file: 16941-06-3.mol

Synonyms:Nitrosonium hexafluoroantimonate;16941-06-3;Nitrosyl hexafluoroantimonate;azanylidyneoxidanium;hexafluoroantimony(1-);MFCD00042550;NOSbF6;NO+SbF6-;DTXSID00587321;Nitrosonium hexafluoroantimonate(V);azylidyneoxonium hexafluorostibate(V);hexafluorostiboranuide;nitrilooxonium;NITROSONIUMHEXAFLUOROANTIMONATE;Nitrilooxidanium hexafluoroantimonate(1-);Nitrosonium hexafluoroantimonate(V) 98%;DB-231508;Nitrosonium hexafluoroantimonate, min. 97%;A811101;hexakis(fluoranyl)antimony(1-);Q61778901;Nitrosonium hexafluoroantimonate, 99.9% trace metals basis

Chemical Property of Nitrosonium hexafluoroantimonate

Chemical Property:

• PSA: 23.79000
• LogP: 2.41748
• Sensitive.: Hygroscopic
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 264.89222
• Heavy Atom Count: 9
• Complexity: 72.7

Purity/Quality:

97% ^*data from raw suppliers

Nitrosonium hexafluoroantimonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn; N; C
• Hazard Codes: Xn,N,C
• Statements: 20/22-51/53
• Safety Statements: 61

MSDS Files:

Useful:

• Canonical SMILES: N#[O+].F[Sb-](F)(F)(F)(F)F

Technology Process of Nitrosonium hexafluoroantimonate

There total 5 articles about Nitrosonium hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(Z)-(15)N2NNFOSbF6 + (E)-(15)N2NNFOSbF6 → nitrogen trifluoride (7783-54-2) + nitrogen-15 (29817-79-6) + nitrosonium hexafluoroantimonate (16941-06-3)

Guidance literature:

In neat (no solvent, solid phase); heated to 50-60°C; NMR; Raman spectroscopy; NMR;

DOI:10.1002/anie.200700130

Reference yield:

N5(1+)*SbF6(1-)=(N5)(1+)[SbF6](1-) (353240-61-6) + nitrogen(II) oxide (10102-43-9) → nitrosonium hexafluoroantimonate (16941-06-3)

Guidance literature:

In neat (no solvent); NO added to Sb deriv. at -196°C (dry box, vacuum line) and warm slowly to room temp.; volatiles pumped off; detd. by vibrational spectroscopy;

DOI:10.1021/ja010141g

Reference yield:

antimony pentafluoride (7783-70-2) + nitrosyl fluoride (7789-25-5) → nitrosonium hexafluoroantimonate (16941-06-3) + 2NO(1+)*SbF7(2-)=(NO)2SbF7

Guidance literature:

In not given; at -78°C;

DOI:10.1021/ja9805728

upstream raw materials:

antimony pentafluoride

nitrosyl fluoride

nitrogen trifluoride

dinitrogen monoxide

Downstream raw materials:

nitrosyl fluoride

lithium hexafluoroantimonate

NO⁽¹⁺⁾*Al(OC(CF₃)2C₆H₅)4^(1-)=NO[Al(OC(CF₃)2C₆H₅)4]