Antimony pentafluoride

Base Information

• Chemical Name: Antimony pentafluoride
• CAS No.: 7783-70-2
• Molecular Formula: F5Sb
• Molecular Weight: 216.742
• Hs Code.: 28261990
• European Community (EC) Number: 232-021-8
• ICSC Number: 0220
• UN Number: 1732
• DSSTox Substance ID: DTXSID00893075
• Wikipedia: Antimony pentafluoride
• Wikidata: Q411381
• Mol file: 7783-70-2.mol

Synonyms:antimony pentafluoride;SbF5 cpd

Chemical Property of Antimony pentafluoride

Chemical Property:

• Appearance/Colour: colourless oily liquid
• Vapor Pressure: 10 mm Hg ( 25 °C)
• Melting Point: 7 °C(lit.)
• Boiling Point: 149.4 °C
• Flash Point: 149.5°C
• PSA: 0.00000
• Density: 2.993 g/mL at 25 °C(lit.)
• LogP: 2.10100
• Storage Temp.: Store below +30°C.
• Sensitive.: Moisture Sensitive
• Solubility.: liquid sulfur dioxide: slightly soluble(lit.)
• Water Solubility.: reacts vigorously with H2O, becoming hydrolyzed [HAW93] [KIR78]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 215.89583
• Heavy Atom Count: 6
• Complexity: 37.1
• Transport DOT Label: Corrosive Poison

Purity/Quality:

98%min ^*data from raw suppliers

Antimony pentafluoride 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,O,C,N,Xn
• Hazard Codes: T,O,C,N,Xn
• Statements: 23/24/25-34-51/53-20/22
• Safety Statements: 61-45-36/37/39-28-27-26-22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Other Toxic Gases & Vapors
• Canonical SMILES: F[Sb](F)(F)(F)F
• Inhalation Risk: A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.
• Effects of Short Term Exposure: Corrosive. Inhalation may cause severe swelling of the throat. This may result in asphyxia. Inhalation may cause lung oedema, but only after initial corrosive effects on eyes and/or airways have become manifest. Exposure at high levels could cause severe lung damage. Medical observation is indicated.
• Effects of Long Term Exposure: The substance may have effects on the cardiovascular system and respiratory tract. This may result in impaired functions.
• Physical properties: Colorless oily liquid; highly viscous; hygroscopic; freezes at 8.3°C; boils at 149.5°C; density 2.99 g/cm3 at 23°C; soluble in excess water (with violent reaction) and glacial acetic acid; also soluble in potassium fluoride.
• Uses: HF/SbF5 is an excellent medium for the preparation of alkylidene oxonium salts.1 In the fluorination of organic Compounds, see the monograph Preparation, Properties and Technology of Fluorine and Organic Fluoro Compounds, C. Slesser, S. R. Schram, Eds. (McGraw-Hill, New York, 1951) 868 pp.

Technology Process of Antimony pentafluoride

There total 46 articles about Antimony pentafluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

antimony (7440-36-0) + trifluoroamine oxide (13847-65-9,57526-95-1,478286-98-5) → antimony pentafluoride (7783-70-2)

Guidance literature:

In neat (no solvent); cylinder fiited with dry powdered element, NF3O condensed into cylinder at -196°C, mixt. heated at 210°C for 24h; not isolated, monitored by NMR, IR;

Reference yield:

antimonypentachloride (7647-18-9) → 2SbF3*SbF5 + antimony(III) chloride (10025-91-9) + antimony pentafluoride (7783-70-2)

Guidance literature:

With HF; byproducts: HCl, Cl2; with anhydrous HF; distn. (8h) at 90 °C (distn. of HCl and HF), and up to 125 °C (distn. of SbCl5, SbCl3 and SbF5); distn. at 390 °C;

Reference yield:

antimony pentoxide + Dichlorodifluoromethane (75-71-8) → antimony tetrachloride fluoride (14913-58-7) + antimony dichloride trifluoride (7791-16-4) + SbF4Cl (15588-48-4) + SbCl3F2 (24626-20-8) + antimony pentafluoride (7783-70-2)

Guidance literature:

In neat (no solvent); reaction at 600°C;;

upstream raw materials:

H₂F⁽¹⁺⁾*SbClF₅^(1-)=H₂FSbClF₅

antimony

xenon difluoride

fluorine

Downstream raw materials:

5-nitro-1-tetralone

5-amino-3,4-dihydronaphthalen-1(2H)-one

potassium hexafluoroantimonate

silver hexafluoroantimonate

Refernces

• 1、 Beattie, Ian,Crocombe, Richard,German, Alun,Jones, Peter,Marsden, Colin,et al.. "". . . Retrieved 1976.
• 2、 Cameron, T. Stanley,Decken, Andreas,Grein, Friedrich,Knapp, Carsten,Passmore, Jack,Rautiainen, J. Mikko,Shuvaev, Konstantin V.,Thompson, Robert C.,Wood, Dale J.. "Preparation and characterization of (CNSSS)2(A)2 (A = AsF6-, SbF6-, Sb2F 11-) containing the O2-like 5,5′-Bis(1,2,3,4-trithiazolium) dication: The second example of a simple nonsterically hindered main-group diradical that retains its paramagnetism in the solid state". . p. 7861 - 7879. Retrieved 2010.
• 3、 Fawcett, John,Holloway, John H.,Laycock, David,Russell, David R.. "Fluoride Ion Donor Properties of UF2O2; Preparation and Characterization of the Adducts UF2O2*nSbF5 (n=2 or 3) and Crystal Structure of UF2O2*3SbF5". . p. 1355 - 1360. Retrieved 1982.
• 4、 Mazej, Zoran,Goreshnik, Evgeny A.. "Crystal Structures of Hydrazinium(II) Salts of [SbF6]- and [Sb2F11]-". . p. 1216 - 1219. Retrieved 2015.
• 5、 Watanabe, Daisuke,Akiyama, Daisuke,Sato, Nobuaki. "Reactions of antimony compounds with fluorine gas by thermogravimetric and differential thermal analyses and X-ray diffraction analysis". . p. 1 - 7. Retrieved 2018/08/06.