Manganese, [29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32]-, (SP-4-1)-

Base Information

• Chemical Name: Manganese, [29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32]-, (SP-4-1)-
• CAS No.: 14325-24-7
• Molecular Formula: C32H16MnN8
• Molecular Weight: 567.471
• Hs Code.: 29310099
• DSSTox Substance ID: DTXSID401015331
• Wikidata: Q3844526
• Mol file: 14325-24-7.mol

Synonyms:Manganese, [29H,31H-phthalocyaninato(2-)-.kappa.N29,.kappa.N30,.kappa.N31,.kappa.N32]-, (SP-4-1)-;DTXSID401015331;J-007781;Q3844526

Chemical Property of Manganese, [29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32]-, (SP-4-1)-

Chemical Property:

• Melting Point: >300 °C
• PSA: 84.02000
• LogP: 1.46440
• Water Solubility.: Soluble in pyridine, chloronaphthalene, and conc. sulfuric acid. Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 567.087836
• Heavy Atom Count: 41
• Complexity: 709

Purity/Quality:

98%,99%, ^*data from raw suppliers

Manganese(II) phthalocyanine, min. 97% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=C5C=CC=CC5=C([N-]4)N=C6C7=CC=CC=C7C(=N6)N=C8C9=CC=CC=C9C(=N8)N=C2[N-]3.[Mn+2]
• Uses: Manganese (II) phthalocyanine is used as a coating of quartz crystals which is to be used as sensors for detecting H2S. It is used to discriminate between cheese varieties, detect volatile hazardous compounds and spoilt fruit.

Technology Process of Manganese, [29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32]-, (SP-4-1)-

There total 19 articles about Manganese, [29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32]-, (SP-4-1)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

phthalonitrile (91-15-6) → manganese (II) phthalocyanine (14325-24-7)

Guidance literature:

With manganese(II) acetate; for 0.166667h; microwave irradiation;

DOI:10.3390/61000831

Reference yield: 45.0%

manganese (II) acetate tetrahydrate (6156-78-1) + phthalonitrile (91-15-6) → manganese(II) phthalocyanin (14325-24-7)

Guidance literature:

In ethanol; at 190 ℃; for 3h; Autoclave; High pressure; Green chemistry;

DOI:10.1016/j.dyepig.2014.08.012

Reference yield: 40.61%

phthalic anhydride (85-44-9) + manganese(II) formate + ammonium chloride (12125-02-9) + urea (57-13-6) → manganese(II) phthalocyanin (14325-24-7)

Guidance literature:

With ammonium dimolybdate; at 140 - 220 ℃; for 6.5h;

DOI:10.3390/molecules27030904

upstream raw materials:

phthalonitrile

oxovanadium phthalocyanine

manganese

manganese(II)

Refernces

• 1、 Hanke. "-". . p. 160,161,162,164. Retrieved 1967.
• 2、 Lever,Wilshire,Quan. "Oxidation of manganese(II) phthalocyanine by molecular oxygen". . p. 761 - 768. Retrieved 1981.
• 3、 Camenzind, Mark J.,Hill, Craig L.. "". . p. 63 - 68. Retrieved 1985.
• 4、 Tan, Amin,Tian, Min,Yang, Yan,Zhang, Gai,Zhang, Yufan. "Effects of MN4-Type Coordination Structure in Metallophthalocyanine for Bio-Inspired Oxidative Desulfurization Performance". . . Retrieved 2022/02/14.
• 5、 -. "One-step thermal reaction of a solvent method of manganese phthalocyanine crystal". Paragraph 0029; 0030. . Retrieved 2017/03/17.