Imidazolidine, 1,3-dimethyl- (7CI,8CI,9CI)

Base Information

• Chemical Name: Imidazolidine, 1,3-dimethyl- (7CI,8CI,9CI)
• CAS No.: 14103-77-6
• Molecular Formula: C5H12 N2
• Molecular Weight: 100.164
• Mol file: 14103-77-6.mol

Synonyms:1,3-Dimethyl-1,3-diazolidine;1,3-Dimethylimidazolidine; N,N'-Dimethylimidazolidine

Chemical Property of Imidazolidine, 1,3-dimethyl- (7CI,8CI,9CI)

Chemical Property:

• Boiling Point: 107℃
• Flash Point: 8℃
• PSA: 6.48000
• Density: 0.903
• LogP: -0.30310

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Imidazolidine, 1,3-dimethyl- (7CI,8CI,9CI)

There total 9 articles about Imidazolidine, 1,3-dimethyl- (7CI,8CI,9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + N,N`-dimethylethylenediamine (110-70-3) → 1,3-dimethylimidazolidine (14103-77-6) + N-formyl-N,N',N'-trimethylethylenediamine (105669-53-2)

Guidance literature:

In water; for 18h; Ambient temperature;

Reference yield: 58.0%

1,3-dimethyl-2-imidazolidinone (80-73-9) → 1,3-dimethylimidazolidine (14103-77-6)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 25 ℃; for 1h;

DOI:10.1021/jo00362a013

Reference yield: 38.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + N,N`-dimethylethylenediamine (110-70-3) → 1,3-dimethylimidazolidine (14103-77-6)

Guidance literature:

With potassium carbonate; In benzene; for 6h;

DOI:10.1016/S0040-4020(97)00922-8

upstream raw materials:

formaldehyd

N,N`-dimethylethylenediamine

1,3-dimethyl-2-imidazolidinone

methanol

Downstream raw materials:

1,4,6,6-Tetramethyl-7-morpholino-2,3,4,5,6,7-hexahydro-1H-1,4-diazepin

4-(diethylamino)butan-2-one

3-diethylamino-1-phenyl-propan-1-one

1-Dimethylamino-3-butanon

Refernces

• 1、 Gueizado-Rodriguez,Ariza-Castolo,Merino,Vela,Noth,Bakhmutov,Contreras. "Weak intramolecular proton-hydride and proton-fluoride interactions: Experimental (NMR, X-ray) and DFT studies of the bis(NBH3) and bis(NBF3) adducts of 1,3-dimethyl-1,3-diazolidine". . p. 9144 - 9152. Retrieved 2001.
• 2、 Nurseiit, Alibek,Janabel, Jaysan,Gudun, Kristina A.,Kassymbek, Aishabibi,Segizbayev, Medet,Seilkhanov, Tulegen M.,Khalimon, Andrey Y.. "Bench-Stable Cobalt Pre-Catalysts for Mild Hydrosilative Reduction of Tertiary Amides to Amines and Beyond". . p. 790 - 798. Retrieved 2019/01/09.