Allylaminotrimethylsilane

Base Information

• Chemical Name: Allylaminotrimethylsilane
• CAS No.: 10519-97-8
• Molecular Formula: C6H15NSi
• Molecular Weight: 129.277
• Hs Code.: 29310099
• European Community (EC) Number: 623-103-8
• DSSTox Substance ID: DTXSID00370013
• Nikkaji Number: J364.718H
• Wikidata: Q82157323
• Mol file: 10519-97-8.mol

Synonyms:ALLYLAMINOTRIMETHYLSILANE;10519-97-8;N-trimethylsilylprop-2-en-1-amine;N-(Trimethylsilyl)allylamine;(prop-2-en-1-yl)(trimethylsilyl)amine;Silanamine,1,1,1-trimethyl-N-2-propen-1-yl-;N-allyl-1,1,1-trimethylsilanamine;Allyl(trimethylsilyl)amine;SCHEMBL435798;DTXSID00370013;MFCD00053866;N-(trimethylsilyl)prop-2-en-1-amine;AKOS015909149;1,1,1-Trimethyl-N-2-Propen-1-Yl-Silanamine;J-001357;(S)-methyl 2-((S)-2-aminopropanamido)-4-methylpentanoate hydrochloride

Chemical Property of Allylaminotrimethylsilane

Chemical Property:

• Appearance/Colour: clear colorless to light yellow liquid
• Vapor Pressure: 36.6mmHg at 25°C
• Melting Point: < 0 °C
• Refractive Index: 1.411-1.416
• Boiling Point: 100.5 °C at 760 mmHg
• PKA: 12.33±0.70(Predicted)
• Flash Point: 14.6 °C
• PSA: 12.03000
• Density: 0.773 g/cm³
• LogP: 1.98780
• Storage Temp.: Flammables area
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 129.097376017
• Heavy Atom Count: 8
• Complexity: 73.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,1,1-Trimethyl-N-2-propen-1-ylsilanamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C, F
• Hazard Codes: C-F,C
• Statements: 34-11
• Safety Statements: 45-36/37/39-25-16-26-23

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)NCC=C
• Uses: 1,1,1-Trimethyl-N-2-propen-1-ylsilanamine is a potential precursor for synthesis of silicon carbonitride films. Also, it is an intermediate used in the synthesis of Z-3-(Tributylstannyl)-2-propen-1-amine (T773980).

Technology Process of Allylaminotrimethylsilane

There total 3 articles about Allylaminotrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

chloro-trimethyl-silane (75-77-4) + 1-amino-2-propene (107-11-9,30551-89-4) → allylamino-trimethyl-silane (10519-97-8)

Guidance literature:

In Petroleum ether; for 3h;

Reference yield: 94.5%

1-amino-2-propene (107-11-9,30551-89-4) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → allylamino-trimethyl-silane (10519-97-8)

Guidance literature:

chloro-trimethyl-silane; at 65 - 70 ℃; for 4h; Product distribution / selectivity;

Reference yield:

→ allylamino-trimethyl-silane (10519-97-8)

Guidance literature:

CH2=CH-CH2NH2, (CH3)3Si-Si(CH3)3 ;

upstream raw materials:

1-amino-2-propene

1,1,1,3,3,3-hexamethyl-disilazane

chloro-trimethyl-silane

Downstream raw materials:

1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane

3-aminopropyltriethoxysilane

N,N-bis(trimethylsilyl)allylamine

1,4-bis(3-aminopropyldimethylsilyl)benzene

Refernces

• 1、 Williard, Paul G.,Jacobson, Madeleine A.. "Dianion aggregates derived from lithiation of N-silyl allylamine". . p. 2753 - 2755. Retrieved 2000.
• 2、 -. "IMPROVED PROCESS FOR PRODUCING BIS-(AMINOALKYL)-POLYSILOXANES". Page/Page column 16-17. . Retrieved 2008/12/07.