(-)-menthyl bicyclo[2.2.1]hept-2-ene-5-carboxylate

Base Information

Chemical Name:(-)-menthyl bicyclo[2.2.1]hept-2-ene-5-carboxylate
CAS No.:138752-03-1
Molecular Formula:C₁₈H₂₈O₂
Molecular Weight:276.419
Hs Code.:

Synonyms:(-)-menthyl bicyclo[2.2.1]hept-2-ene-5-carboxylate

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Chemical Property of (-)-menthyl bicyclo[2.2.1]hept-2-ene-5-carboxylate

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Technology Process of (-)-menthyl bicyclo[2.2.1]hept-2-ene-5-carboxylate

There total 7 articles about (-)-menthyl bicyclo[2.2.1]hept-2-ene-5-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 120-74-1,934-30-5,1195-12-6,20507-53-3,58001-99-3,67999-50-2,67999-53-5,74645-32-2,108266-75-7
(1S,2S,4S)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid

: 2216-51-5
(-)-menthol

: 138752-03-1
(-)-menthyl bicyclo[2.2.1]hept-2-ene-5-carboxylate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 - 20 ℃; for 3.08333h;
DOI:10.1021/jacs.7b01747

Reference yield: 60.0%

: 4835-96-5
(-)-menthyl acrylate

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 138752-03-1
(-)-menthyl bicyclo[2.2.1]hept-2-ene-5-carboxylate

Guidance literature:: With boron tribromide; In dichloromethane; at -78 ℃; for 0.5h;
DOI:10.1023/A:1012374828303

Reference yield:

: 4835-96-5
(-)-menthyl acrylate

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 138752-03-1
(-)-menthyl bicyclo[2.2.1]hept-2-ene-5-carboxylate

: 138752-04-2
(1S,2R,4S)-Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

: 84235-36-9
(1R,2R,4R)-Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

: 84235-35-8
(1R,2S,4R)-Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Guidance literature:: With diethylaluminium chloride; In toluene; at 20 ℃; for 2.5h; Product distribution; other chiral acrylates; other silica and alumina modified by Lewis acids; var. reaction times and temperatures;
DOI:10.1016/S0957-4166(00)80163-9