t-Butyltrichlorogermane

Base Information

Chemical Name:t-Butyltrichlorogermane
CAS No.:1184-92-5
Molecular Formula:C₄H₉Cl₃Ge
Molecular Weight:236.064
Hs Code.:2931900090
DSSTox Substance ID:DTXSID20516597
Nikkaji Number:J1.057.560E
Wikidata:Q82378080
Mol file:1184-92-5.mol

Synonyms:t-Butyltrichlorogermane;1184-92-5;tert-Butyl(trichloro)germane;TERT-BUTYLTRICHLOROGERMANE;Germane,trichloro(1,1-dimethylethyl)-;SCHEMBL1456366;DTXSID20516597;trichloro(1,1-dimethylethyl)-germane;FT-0740693;J-003763

Suppliers and Price of t-Butyltrichlorogermane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 16 raw suppliers

Chemical Property of t-Butyltrichlorogermane

Chemical Property:

Vapor Pressure:2.97mmHg at 25°C
Melting Point:94-95°C
Boiling Point:169-70°C
Flash Point:>65°C
PSA：0.00000
LogP:3.44180
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:235.898161
Heavy Atom Count:8
Complexity:78.3

Purity/Quality:: 98%,99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 34
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Ge](Cl)(Cl)Cl

Technology Process of t-Butyltrichlorogermane

There total 7 articles about t-Butyltrichlorogermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: germanium dichloride ethanol adduct

: 75-65-0
tert-butyl alcohol

: 1184-92-5
tert-butyltrichlorogermane

Guidance literature:: In hydrogenchloride; ethanol; conc. HCl addn. to ethanol soln. of Ge-compd., warming (35 to 40°C), t-BuOH addn., heating (110 to 120°C, 7 h); cooling to room temperature, lower layer distillation;

Reference yield: 60.0%

: 507-20-0
tertiary butyl chloride

: 1184-65-2
germanium hydride trichloride

: 1184-92-5
tert-butyltrichlorogermane

Guidance literature:: In diethyl ether; ligand in Et2O was added to soln. of GeCl3H in Et2O at 0°C, stired at 0°C for 1 d; concd., pentane was slowly added, recrystd. from Et2O;
DOI:10.1016/S0022-328X(02)02157-5

Reference yield: 47.0%

: germanium(II) chloride dioxane

: 75-65-0
tert-butyl alcohol

: 1184-92-5
tert-butyltrichlorogermane

Guidance literature:: With zinc(II) chloride; In 1,4-dioxane; in the presence of ZnCl2 impurities, refluxing (110°C, 16 h); cooling, filtration, lower layer distillation in vacuum;