RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2

Base Information

• Chemical Name: RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2
• CAS No.: 387878-94-6
• Molecular Formula: C₂₉H₃₅ClF₁₂OP₂Ru
• Molecular Weight: 826.048
• Mol file: 387878-94-6.mol

Synonyms:RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2

Chemical Property of RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2

There total 4 articles about RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

methanol (67-56-1) + ruthenium(III) chloride trihydrate (14898-67-0) + P(i)Pr2[3,5-(CF3)2C6H3] (387878-90-2) → RuHCl(CO)(P(i)Pr2[3,5-CF3)2C6H3])2 (387878-94-6)

Guidance literature:

With Na₂CO₃; In methanol; RuCl3*3H2O (1.9 mmol) was mixed with a ligand (6 mmol) and Na2CO3 (2 mmol); methanol was added; the soln. was refluxed at 70°C for 8 h; under Ar; volatiles were removed in vac.; the solid was dissolved in benzene and filtered via glass wool; benzene was removed in vac. and the residue was washed with pentane; NMR-, IR studies;

DOI:10.1021/ic000500t

Reference yield: 61.0%

ruthenium(III) chloride trihydrate (14898-67-0) + 2-methoxy-ethanol (109-86-4,95507-80-5) + triethylamine (121-44-8) + P(i)Pr2[3,5-(CF3)2C6H3] (387878-90-2) → RuHCl(CO)(P(i)Pr2[3,5-CF3)2C6H3])2 (387878-94-6) + [RuCl2(CO)(P(i)Pr2[3,5-CF3)2C6H3])2] + [NEt3H][RuHCl2(CO)(P(i)Pr2[3,5-CF3)2C6H3])2] (387878-93-5)

Guidance literature:

In 2-methoxy-ethanol; RuCl3*3H2O (6.4 mmol) was mixed with triethylamine (15 mmol) and a ligand (20 mmol); 2-methoxyethanol was added; the soln. was heated at 120°C for 21 h under Ar; volatiles were removed in vac.; the residue was dissolved in a min. amt.of hot toluene; pentane was added; cooling to -40°C; it was filt ered and washed with pentane; recrystn. from toluene-pentane mixt.; NMR-, IR studies;

DOI:10.1021/ic000500t

Reference yield:

ruthenium(II)H(Cl)(CO)(CH2CH3)(P-iPr2(3,5-(CF3)2-C6H3))2 → ruthenium(II)H(Cl)(CO)(P-iPr2(3,5-(CF3)2-C6H3))2 (387878-94-6)

Guidance literature:

In benzene-d6; byproducts: C2H2; ethylene removed by four freeze-pump-thaw cycles; not isolated, detected by NMR spectroscopy;

DOI:10.1039/b103113a

upstream raw materials:

methanol

ruthenium(III) chloride trihydrate

triethylamine

P(i)Pr₂[3,5-(CF₃)2C₆H₃]

Downstream raw materials:

RuHCl(HNO)(CO)(P(i)Pr₂(3,5-(CF₃)2C₆H₃))2

[Bu₄N][RuHCl₂(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2]