RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2

Base Information

Chemical Name:RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2
CAS No.:387878-94-6
Molecular Formula:C₂₉H₃₅ClF₁₂OP₂Ru
Molecular Weight:826.048
Hs Code.:

RuHCl(CO)(P(i)Pr<sub>2</sub>[3,5-CF<sub>3</sub>)2C<sub>6</sub>H<sub>3</sub>])2

Synonyms:RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2

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Chemical Property of RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2

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Technology Process of RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2

There total 4 articles about RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 67-56-1
methanol

: 14898-67-0
ruthenium(III) chloride trihydrate

: 387878-90-2
P(i)Pr₂[3,5-(CF₃)2C₆H₃]

: 387878-94-6
RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2

Guidance literature:: With Na₂CO₃; In methanol; RuCl3*3H2O (1.9 mmol) was mixed with a ligand (6 mmol) and Na2CO3 (2 mmol); methanol was added; the soln. was refluxed at 70°C for 8 h; under Ar; volatiles were removed in vac.; the solid was dissolved in benzene and filtered via glass wool; benzene was removed in vac. and the residue was washed with pentane; NMR-, IR studies;
DOI:10.1021/ic000500t

Reference yield: 61.0%

: 14898-67-0
ruthenium(III) chloride trihydrate

: 109-86-4,95507-80-5
2-methoxy-ethanol

: 121-44-8
triethylamine

: 387878-90-2
P(i)Pr₂[3,5-(CF₃)2C₆H₃]

: 387878-94-6
RuHCl(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2

: [RuCl₂(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2]

: 387878-93-5
[NEt₃H][RuHCl₂(CO)(P(i)Pr₂[3,5-CF₃)2C₆H₃])2]

Guidance literature:: In 2-methoxy-ethanol; RuCl3*3H2O (6.4 mmol) was mixed with triethylamine (15 mmol) and a ligand (20 mmol); 2-methoxyethanol was added; the soln. was heated at 120°C for 21 h under Ar; volatiles were removed in vac.; the residue was dissolved in a min. amt.of hot toluene; pentane was added; cooling to -40°C; it was filt ered and washed with pentane; recrystn. from toluene-pentane mixt.; NMR-, IR studies;
DOI:10.1021/ic000500t

Reference yield:

: ruthenium(II)H(Cl)(CO)(CH₂CH₃)(P-iPr₂(3,5-(CF₃)2-C₆H₃))2

: 387878-94-6
ruthenium(II)H(Cl)(CO)(P-iPr₂(3,5-(CF₃)2-C₆H₃))2

Guidance literature:: In benzene-d6; byproducts: C2H2; ethylene removed by four freeze-pump-thaw cycles; not isolated, detected by NMR spectroscopy;
DOI:10.1039/b103113a