2,2-DIALLYL-PYRROLIDINE

Base Information

• Chemical Name: 2,2-DIALLYL-PYRROLIDINE
• CAS No.: 40162-97-8
• Molecular Formula: C₁₀H₁₇N
• Molecular Weight: 151.252
• Mol file: 40162-97-8.mol

Synonyms:2,2-di(2-propenyl)pyrrolidine

Chemical Property of 2,2-DIALLYL-PYRROLIDINE

Chemical Property:

• Vapor Pressure: 0.496mmHg at 25°C
• Boiling Point: 192.2±9.0 °C(Predicted)
• PKA: 11.85±0.10(Predicted)
• Density: 0.833±0.06 g/cm3(Predicted)

Purity/Quality:

98%min ^*data from raw suppliers

2,2-diallylpyrrolidine ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,Xn
• Statements: 22

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,2-DIALLYL-PYRROLIDINE

There total 3 articles about 2,2-DIALLYL-PYRROLIDINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-pyrrolidinon (616-45-5) + allyl bromide (106-95-6) → 2,2-di(2-propenyl)pyrrolidine (40162-97-8)

Guidance literature:

allyl bromide; With samarium; In tetrahydrofuran; at 20 ℃; for 1h;

2-pyrrolidinon; In tetrahydrofuran; at 20 ℃; for 0.0833333h;

DOI:10.1016/S0040-4039(01)01831-7 DOI:10.1016/S0040-4020(02)00491-X

Reference yield: 90.0%

2-pyrrolidinon (616-45-5) + Triallylborane (688-61-9,53588-88-8,90721-85-0,151452-33-4,151452-35-6) → 2,2-di(2-propenyl)pyrrolidine (40162-97-8)

Guidance literature:

In tetrahydrofuran; for 1.5h; Heating;

DOI:10.1002/(sici)1099-0690(200004)2000:8<1503::aid-ejoc1503>3.0.co;2-7

Reference yield:

→ 2,2-di(2-propenyl)pyrrolidine (40162-97-8)

Guidance literature:

2-Ethoxypyrrolin (23), Allylbromid, Mg, I2;

DOI:10.1021/ja00842a031

upstream raw materials:

2-pyrrolidinon

Triallylborane

allyl bromide

Downstream raw materials:

1-benzyl-2,2-di(2-propenyl)pyrrolidine

1-benzyl-10-azaspiro[4.4]non-7-ene

1-(trifluoroacetyl)-1-azaspiro[4.4]non-7-ene

Refernces

• 1、 Bubnov, Yu. N.,Spiridonov, Yu. Ya.,Kuznetsov, N. Yu.. "New growth regulators of corn based on N-mono- and N,N-bis-3-butenyldichloroacetamides". . p. 345 - 358. Retrieved 2018/05/22.
• 2、 Li, Zhifang,Zhang, Yongmin. "Direct construction of a quaternary carbon center utilizing an organosamarium reagent". . p. 8507 - 8510. Retrieved 2007/10/03.