dicarbonylcyclopentadienyl(p-methoxyphenyl)iron

Base Information

• Chemical Name: dicarbonylcyclopentadienyl(p-methoxyphenyl)iron
• CAS No.: 33308-64-4
• Molecular Formula: C₁₄H₁₂FeO₃
• Molecular Weight: 284.094
• Mol file: 33308-64-4.mol

Synonyms:dicarbonylcyclopentadienyl(p-methoxyphenyl)iron

Chemical Property of dicarbonylcyclopentadienyl(p-methoxyphenyl)iron

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of dicarbonylcyclopentadienyl(p-methoxyphenyl)iron

There total 7 articles about dicarbonylcyclopentadienyl(p-methoxyphenyl)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) + 4-MeOC6H4ZnI*LiCl → dicarbonylcyclopentadienyl(p-methoxyphenyl)iron (33308-64-4)

Guidance literature:

With palladium diacetate; In tetrahydrofuran; under Ar atm. Fe complex, Pd(OAc)2, diamine, and arylzinc iodide -LiCl complex in THF were stirred at 0°C for 15 min; aq. NH4Cl was added, product was extd. with EtOAc, passed through Na2SO4/Florisil pad and chromd. on silica (CS2);

DOI:10.1021/om800916r

Reference yield: 92.0%

[rhodium(I)chloride(triphenylphosphine)2]1 (14653-50-0) + [Fe(η(5)-C5H5)(CO)2(C(O)-p-C6H4OMe)] + acetonitrile (75-05-8,26809-02-9) → trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8) + dicarbonylcyclopentadienyl(p-methoxyphenyl)iron (33308-64-4)

Guidance literature:

In acetonitrile; N2-atmosphere;

DOI:10.1016/S0020-1693(00)94702-9

Reference yield: 82.0%

dicarbonylcyclopentadienyliodoiron(II) (12078-28-3,38979-86-1) + 4-methoxyphenylboronic acid (5720-07-0) → dicarbonylcyclopentadienyl(p-methoxyphenyl)iron (33308-64-4)

Guidance literature:

With copper(l) iodide; caesium carbonate; [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride; In 1,4-dioxane; under Ar atm. Fe complex, arylboronic acid, catalyst, CuI and Cs2CO3 in 1,4-dioxane were heated at 60°C for 4 h; aq. NH4Cl was added, product was chromd. on silica (CS2);

DOI:10.1021/om800916r

upstream raw materials:

Wilkinson's catalyst

[rhodium(I)chloride(triphenylphosphine)2]1

acetonitrile

dicarbonylcyclopentadienyliodoiron(II)

Downstream raw materials:

p-methoxystilbene