POLY(CYCLOHEXYL ACRYLATE)

Base Information

• Chemical Name: POLY(CYCLOHEXYL ACRYLATE)
• CAS No.: 27458-65-7
• Molecular Formula: C9H14O2
• Molecular Weight: 154.21
• Mol file: 27458-65-7.mol

Synonyms:POLY(CYCLOHEXYL ACRYLATE)

Chemical Property of POLY(CYCLOHEXYL ACRYLATE)

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of POLY(CYCLOHEXYL ACRYLATE)

There total 8 articles about POLY(CYCLOHEXYL ACRYLATE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

acryloyl chloride (814-68-6,25189-84-8) + cyclohexanol (108-93-0) → cyclohexyl acrylate (3066-71-5,27458-65-7)

Guidance literature:

With triethylamine; In tetrahydrofuran; for 2h;

DOI:10.1021/jf0499018

Reference yield: 78.0%

acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + cyclohexanol (108-93-0) → cyclohexyl acrylate (3066-71-5,27458-65-7)

Guidance literature:

With oxo[hexa(trifluoroacetato)]tetrazinc; C₁₉H₂₄N₄O; In di-isopropyl ether; for 18h; Reflux;

Reference yield: 23.0%

acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + cyclohexanol (108-93-0) → methyl 3-methoxypropionate (3852-09-3) + cyclohexyl acrylate (3066-71-5,27458-65-7) + 3-Methoxy-propionic acid cyclohexyl ester (112032-53-8)

Guidance literature:

With n-butyllithium; bis(acetylacetonate)nickel(II); In benzene; at 90 ℃; for 5h; Product distribution;

upstream raw materials:

acrylic acid methyl ester

cyclohexanol

acrylic acid

cyclohexene

Downstream raw materials:

2,3-dichloro-propionic acid cyclohexyl ester

c-hexyl pyruvate

(Z)-cyclohexyl 2-bromo-3-(phenylamino)acrylate

(E)-cyclohexyl 2-bromo-3-(phenylamino)acrylate

Refernces

• 1、 -. "METHOD FOR PRODUCING DICARBOXYLIC ACID". Paragraph 0116. . Retrieved 2021/05/21.
• 2、 Guo, Hongchao,Li, Hongxiang,Liu, Hao,Shi, Wangyu,Wang, Chang,Wang, Wei,Wu, Yongjun. "Phosphine-Catalyzed Cascade Annulation of MBH Carbonates and Diazenes: Synthesis of Hexahydrocyclopenta[c]pyrazole Derivatives". supporting information. p. 5571 - 5575. Retrieved 2021/07/31.