Methyl 3-acetoxy-2-methylenebutyrate

Base Information

Chemical Name:Methyl 3-acetoxy-2-methylenebutyrate
CAS No.:22787-68-4
Molecular Formula:C8H12 O4
Molecular Weight:172.18
Hs Code.:2918990090
DSSTox Substance ID:DTXSID30408353
Nikkaji Number:J590.644J
Mol file:22787-68-4.mol

Synonyms:Methyl 3-acetoxy-2-methylenebutyrate;22787-68-4;methyl 3-acetyloxy-2-methylidenebutanoate;methyl 3-acetoxy-2-methylenebutanoate;starbld0036396;SCHEMBL2465319;DTXSID30408353;RECQPQVWZPJQJO-UHFFFAOYSA-N;methyl 2-(1-acetoxyethyl)acrylate;methyl-3-acetoxy-2-methylenebutyrate;Methyl 3-acetoxy-2-methylenebutyrate, 98%;J-014853

Suppliers and Price of Methyl 3-acetoxy-2-methylenebutyrate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Methyl 3-acetoxy-2-methylenebutyrate 98%
1g
$ 43.80

American Custom Chemicals Corporation
Methyl 3-acetoxy-2-methylenebutyrate 95.00%
1G
$ 647.00

Total 5 raw suppliers

Chemical Property of Methyl 3-acetoxy-2-methylenebutyrate

Chemical Property:

Vapor Pressure:0.09mmHg at 25°C
Refractive Index:n20/D 1.436(lit.)
Boiling Point:65-69 °C1 mm Hg(lit.)
Flash Point:188 °F
PSA：52.60000
Density:1.069 g/mL at 25 °C(lit.)
LogP:0.66720
Storage Temp.:2-8°C
XLogP3:0.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:172.07355886
Heavy Atom Count:12
Complexity:207

Purity/Quality:

99% ^*data from raw suppliers

Methyl 3-acetoxy-2-methylenebutyrate 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C(=C)C(=O)OC)OC(=O)C

Technology Process of Methyl 3-acetoxy-2-methylenebutyrate

There total 5 articles about Methyl 3-acetoxy-2-methylenebutyrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 98837-36-6,111002-28-9,112572-93-7,18020-65-0
methyl 3-hydroxy-2-methylenebutyrate

: 108-24-7
acetic anhydride

: 22787-68-4
methyl 2-(1-acetoxyethyl)acrylate

Guidance literature:: With pyridine; In dichloromethane; at -15 - 0 ℃;
DOI:10.1021/jo701415m

Reference yield: 67.0%

: 98837-36-6,111002-28-9,112572-93-7,18020-65-0
methyl 3-hydroxy-2-methylenebutyrate

: 75-36-5
acetyl chloride

: 22787-68-4
methyl 2-(1-acetoxyethyl)acrylate

Guidance literature:: With pyridine; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1021/jo00120a009

Reference yield:

: 67-56-1
methanol

: 16169-82-7
(+/-)-3-acetyloxy-1-butyne

: 201230-82-2
carbon monoxide

: 22787-68-4
methyl 2-(1-acetoxyethyl)acrylate

Guidance literature:: With diphenyl-(6-methyl-pyridin-2-yl)phosphine; In 1,2-dichloro-ethane; at 50 ℃; for 4h; under 22801.5 Torr; Reagent/catalyst; Temperature; Catalytic behavior; Autoclave; Inert atmosphere; Schlenk technique;
DOI:10.1016/j.mcat.2020.111179