3-methyloxetane

Base Information

• Chemical Name: 3-methyloxetane
• CAS No.: 2167-38-6
• Molecular Formula: C4H8O
• Molecular Weight: 72.1069
• Hs Code.: 2932999099
• Mol file: 2167-38-6.mol

Synonyms:Propane,1,3-epoxy-2-methyl- (8CI);3-Methyloxetane;

Chemical Property of 3-methyloxetane

Chemical Property:

• Boiling Point: 59 °C at 760 mmHg
• PSA: 9.23000
• Density: 0.879 g/cm³
• LogP: 0.65270

Purity/Quality:

98%min ^*data from raw suppliers

3-METHYLOXETANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-methyloxetane

There total 5 articles about 3-methyloxetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

<3-Brom-2-methyl-propoxy-(1)>-tributyl-zinn (40894-10-8) → 3-methyloxetane (2167-38-6) + tributyltin bromide (1461-23-0)

Guidance literature:

decompn. at 200°C (0.5 h);

DOI:10.1016/S0022-328X(00)81744-1 DOI:10.1016/S0040-4039(01)88092-8

Reference yield:

trimethylene oxide (503-30-0) + diazomethane (186581-53-3,908094-01-9,334-88-3) + methanol (67-56-1) → 3-methyloxetane (2167-38-6) + tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + (+/-)-2-methyloxetane (2167-39-7) + methylallylether (627-40-7)

Guidance literature:

Yield given. Further byproducts given. Yields of byproduct given; Irradiation;

DOI:10.1016/S0040-4039(00)61877-4

Reference yield:

trimethylene oxide (503-30-0) + diazomethane (186581-53-3,908094-01-9,334-88-3) → 3-methyloxetane (2167-38-6) + tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + (+/-)-2-methyloxetane (2167-39-7) + methylallylether (627-40-7)

Guidance literature:

Yield given. Yields of byproduct given; Irradiation;

DOI:10.1016/S0040-4039(00)61877-4

upstream raw materials:

trimethylene oxide

diazomethane

methanol

<3-Brom-2-methyl-propoxy-(1)>-tributyl-zinn

Downstream raw materials:

1,2-propylene cyclic carbonate

4-Tributylstannyl-2-butanol

formaldehyd

propene

Refernces