Acetic acid (E)-3-(2-formylamino-4-methanesulfonyloxy-phenyl)-allyl ester

Base Information

Chemical Name:Acetic acid (E)-3-(2-formylamino-4-methanesulfonyloxy-phenyl)-allyl ester
CAS No.:287980-07-8
Molecular Formula:C₁₃H₁₅NO₆S
Molecular Weight:313.331
Hs Code.:

Synonyms:Acetic acid (E)-3-(2-formylamino-4-methanesulfonyloxy-phenyl)-allyl ester

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Chemical Property of Acetic acid (E)-3-(2-formylamino-4-methanesulfonyloxy-phenyl)-allyl ester

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Technology Process of Acetic acid (E)-3-(2-formylamino-4-methanesulfonyloxy-phenyl)-allyl ester

There total 10 articles about Acetic acid (E)-3-(2-formylamino-4-methanesulfonyloxy-phenyl)-allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 20455-07-6
p-nitrophenyl methanesulfonate

: 287980-07-8
Acetic acid (E)-3-(2-formylamino-4-methanesulfonyloxy-phenyl)-allyl ester

Guidance literature:: Multi-step reaction with 10 steps

1.1: H₂ / 10 percent Pd/C / methanol / 1 h / 20 °C

2.1: 0.33 h / 70 °C

3.1: HNO₃ / 0.5 h / 0 °C

4.1: HCl / methanol / 2 h / 70 °C

5.1: NaNO₂; aq. HCl / ethyl acetate / -15 °C

5.2: KI / ethyl acetate / 0.25 h / -15 °C

6.1: 83 percent / BnEt₃NCl / Pd(OAc)2 / dimethylformamide / 2 h / 50 °C

7.1: NaBH₄ / methanol / 0.5 h / -15 °C

8.1: pyridine / 0.25 h / 20 °C

9.1: Zn; AcOH / CH₂Cl₂ / 0.5 h / 20 °C

10.1: Ac₂O / CH₂Cl₂ / 0.5 h / 0 °C

With pyridine; hydrogenchloride; sodium tetrahydroborate; N-benzyl-N,N,N-triethylammonium chloride; hydrogen; nitric acid; acetic anhydride; acetic acid; zinc; sodium nitrite; palladium diacetate; palladium on activated charcoal; In methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 1.1: Catalytic hydrogenation / 2.1: Acetylation / 3.1: Nitration / 4.1: Deacetylation / 5.1: Diazotization / 5.2: Iodination / 6.1: phosphine-free Heck reaction / 7.1: Reduction / 8.1: Acetylation / 9.1: Reduction / 10.1: Formylation;

Reference yield:

: 22821-80-3
methanesulfonic acid 4-acetamidophenyl ester

: 287980-07-8
Acetic acid (E)-3-(2-formylamino-4-methanesulfonyloxy-phenyl)-allyl ester

Guidance literature:: Multi-step reaction with 8 steps

1.1: HNO₃ / 0.5 h / 0 °C

2.1: HCl / methanol / 2 h / 70 °C

3.1: NaNO₂; aq. HCl / ethyl acetate / -15 °C

3.2: KI / ethyl acetate / 0.25 h / -15 °C

4.1: 83 percent / BnEt₃NCl / Pd(OAc)2 / dimethylformamide / 2 h / 50 °C

5.1: NaBH₄ / methanol / 0.5 h / -15 °C

6.1: pyridine / 0.25 h / 20 °C

7.1: Zn; AcOH / CH₂Cl₂ / 0.5 h / 20 °C

8.1: Ac₂O / CH₂Cl₂ / 0.5 h / 0 °C

With pyridine; hydrogenchloride; sodium tetrahydroborate; N-benzyl-N,N,N-triethylammonium chloride; nitric acid; acetic anhydride; acetic acid; zinc; sodium nitrite; palladium diacetate; In methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 1.1: Nitration / 2.1: Deacetylation / 3.1: Diazotization / 3.2: Iodination / 4.1: phosphine-free Heck reaction / 5.1: Reduction / 6.1: Acetylation / 7.1: Reduction / 8.1: Formylation;

Reference yield:

: 24690-19-5
methanesulfonic acid 4-aminophenyl ester

: 287980-07-8
Acetic acid (E)-3-(2-formylamino-4-methanesulfonyloxy-phenyl)-allyl ester

Guidance literature:: Multi-step reaction with 9 steps

1.1: 0.33 h / 70 °C

2.1: HNO₃ / 0.5 h / 0 °C

3.1: HCl / methanol / 2 h / 70 °C

4.1: NaNO₂; aq. HCl / ethyl acetate / -15 °C

4.2: KI / ethyl acetate / 0.25 h / -15 °C

5.1: 83 percent / BnEt₃NCl / Pd(OAc)2 / dimethylformamide / 2 h / 50 °C

6.1: NaBH₄ / methanol / 0.5 h / -15 °C

7.1: pyridine / 0.25 h / 20 °C

8.1: Zn; AcOH / CH₂Cl₂ / 0.5 h / 20 °C

9.1: Ac₂O / CH₂Cl₂ / 0.5 h / 0 °C

With pyridine; hydrogenchloride; sodium tetrahydroborate; N-benzyl-N,N,N-triethylammonium chloride; nitric acid; acetic anhydride; acetic acid; zinc; sodium nitrite; palladium diacetate; In methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 1.1: Acetylation / 2.1: Nitration / 3.1: Deacetylation / 4.1: Diazotization / 4.2: Iodination / 5.1: phosphine-free Heck reaction / 6.1: Reduction / 7.1: Acetylation / 8.1: Reduction / 9.1: Formylation;