(R)-Monophos

Base Information

Chemical Name:(R)-Monophos
CAS No.:185449-80-3
Molecular Formula:C₂₂H₁₈NO₂P
Molecular Weight:359.364
Hs Code.:
European Community (EC) Number:811-204-1
Nikkaji Number:J2.099.152F,J695.548G,J2.343.369I

Synonyms:(R)-Monophos;157488-65-8;185449-80-3;(R)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;345967-22-8;(S)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine;(S)-Monophos;N,N-DIMETHYLDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE;R-MonoPhos;S-MonoPhos;MFCD03426988;(R)-(-)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine;(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;N,N-dimethyl-12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine;(+/-)-MonoPhos;(R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine,;(+/-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;C22H18NO2P;()-MonoPhos;SCHEMBL973485;VNA96722;AC9125;AKOS015918434;CS-W008148;SC11369;Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-dimethyl-, (11bR)-;AS-73532;BP-12203;BP-12204;SY009833;SY226298;CS-0062403;D4992;D4993;FT-0701461;FT-0701641;F17178;F20292;A852730;A874927;J-011898;1,1'-Binaphthalene-2,2'-diyldioxyphosphinodimethylamine;(aR)-4-(Dimethylamino)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(aS)-4-(Dimethylamino)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;()-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;N,N-DIMETHYLDINAPHTHO[2,1-D:1?,2?-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE;(R)-(-)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, 97%;(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4- a inverted exclamation mark ]dinaphthalen-4-yl)dimethylamine;3,4- a']dinaphthalen-4-yl)dimethylamine, 97%;N,N-dimethyl-12,14-dioxa-13-phosphapentacyclo[13.8.0.0(2),(1)(1).0(3),?.0(1)?,(2)(3)]tricosa-1(15),2(11),3(8),4,6,9,16,18(23),19,21-decaen-13-amine;N,N-dimethyl-12,14-dioxa-13-phosphapentacyclo[13.8.0.0^{2,11.0^{3,8.0^{18,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine;N,N-Dimethyldinaphtho[2,1-d:1 inverted exclamation mark ,2 inverted exclamation mark -f][1,3,2]dioxaphosphepin-4-amine

Suppliers and Price of (R)-Monophos

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(S)-N,N-Dimethyldinaphtho[2,1-d:1'',2''-f][1,3,2]dioxaphosphepin-4-amine
100mg
$ 75.00

TCI Chemical
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4- a′]dinaphthalen-4-yl)dimethylamine >98.0%(HPLC)(T)
1g
$ 43.00

TCI Chemical
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4- a′]dinaphthalen-4-yl)dimethylamine >98.0%(HPLC)(T)
5g
$ 146.00

Strem Chemicals
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (S)-MONOPHOS
250mg
$ 24.00

Strem Chemicals
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)dimethylamine, min. 97% (S)-MONOPHOS
1g
$ 72.00

Sigma-Aldrich
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4- a′]dinaphthalen-4-yl)dimethylamine 97%
1g
$ 53.10

Sigma-Aldrich
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4- a′]dinaphthalen-4-yl)dimethylamine 97%
250mg
$ 24.30

Sigma-Aldrich
(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4- a′]dinaphthalen-4-yl)dimethylamine 97%
5g
$ 168.00

Crysdot
(S)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine 95+%
25g
$ 420.00

ChemScene
(S)-N,N-Dimethyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine >97.0%
5g
$ 94.00

Total 36 raw suppliers

Chemical Property of (R)-Monophos

Chemical Property:

Melting Point:190 °C (dec.)
Boiling Point:548.7±33.0 °C(Predicted)
PKA:1.22±0.20(Predicted)
PSA：35.29000
LogP:6.21970
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Sensitive.:moisture sensitive
XLogP3:6.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:359.10751581
Heavy Atom Count:26
Complexity:461

Purity/Quality:

97% ^*data from raw suppliers

(S)-N,N-Dimethyldinaphtho[2,1-d:1'',2''-f][1,3,2]dioxaphosphepin-4-amine ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 22-24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CN(C)P1OC2=C(C3=CC=CC=C3C=C2)C4=C(O1)C=CC5=CC=CC=C54
Uses 1. Asymmetric hydrogenation of ketones and β-keto esters. 2. Light-induced, enantioselective hydrogenation. DSM MonoPhos Family of Highly Efficient Privileged Ligands

Technology Process of (R)-Monophos

There total 2 articles about (R)-Monophos which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%