4-tert-butylphenyl propanoate

Base Information

• Chemical Name: 4-tert-butylphenyl propanoate
• CAS No.: 35154-02-0
• Molecular Formula: C13H18 O2
• Molecular Weight: 206.285
• Mol file: 35154-02-0.mol

Synonyms:Phenol,4-(1,1-dimethylethyl)-, propanoate (9CI); 4-tert-Butylphenyl propionate; NSC6040; p-tert-Butylphenyl propionate

Chemical Property of 4-tert-butylphenyl propanoate

Chemical Property:

• Vapor Pressure: 0.00544mmHg at 25°C
• Boiling Point: 274.3°Cat760mmHg
• Flash Point: 101.5°C
• Density: 0.981g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-tert-butylphenyl propanoate

There total 6 articles about 4-tert-butylphenyl propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-bromophenyl propionate (23600-77-3) + tert-butylmagnesium chloride (677-22-5) → phenyl propionate (637-27-4,132899-52-6) + C13H18O2 (950994-33-9) + ethyl 4-(tert-butyl)benzoate (35154-02-0)

Guidance literature:

tert-butylmagnesium chloride; With bis(acetylacetonate)nickel(II); lithium tert-butoxide; In tetrahydrofuran; at 0 ℃; for 0.166667h; Inert atmosphere;

4-bromophenyl propionate; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/chem.201100909

Reference yield:

ethene (74-85-1) + para-tert-butylphenol (98-54-4) → ethyl 4-(tert-butyl)benzoate (35154-02-0)

Guidance literature:

With carbonyl nickel; benzene; at 320 ℃; under 441305 - 514855 Torr;

Reference yield:

4-bromophenyl propionate (23600-77-3) + tert-butylmagnesium chloride (677-22-5) → C13H18O2 (950994-33-9) + ethyl 4-(tert-butyl)benzoate (35154-02-0)

Guidance literature:

tert-butylmagnesium chloride; With bis(acetylacetonate)nickel(II); 1-(2-carboxyethyl)-3-mesityl-1H-imidazol-3-ium chloride; lithium tert-butoxide; In tetrahydrofuran; diethyl ether; at 0 ℃; for 0.166667h; Inert atmosphere;

4-bromophenyl propionate; In tetrahydrofuran; diethyl ether; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/chem.201100909

upstream raw materials:

ethene

para-tert-butylphenol

propionyl chloride

propionic acid anhydride

Downstream raw materials:

1-(5-tert-butyl-2-hydroxy-phenyl)-propan-1-one

4-tert-Butyl-2-α-hydroxypropyl-anisol

2-propionyl-4-tert-butylanisole

1-(3-bromo-5-tert-butyl-2-hydroxy-phenyl)-propan-1-one