Methyl 4,7-anhydro-2,3-dideoxy-7-phenylheptonate

Base Information

Chemical Name:Methyl 4,7-anhydro-2,3-dideoxy-7-phenylheptonate
CAS No.:204975-45-1
Molecular Formula:C₁₄H₁₈O₅
Molecular Weight:266.294
Hs Code.:
DSSTox Substance ID:DTXSID30693964
Wikidata:Q82622961
Mol file:204975-45-1.mol

Synonyms:DTXSID30693964;Methyl 4,7-anhydro-2,3-dideoxy-7-phenylheptonate

Suppliers and Price of Methyl 4,7-anhydro-2,3-dideoxy-7-phenylheptonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Cayman Chemical
(+)-Goniothalesdiol ≥98%
5mg
$ 351.00

Cayman Chemical
(+)-Goniothalesdiol ≥98%
10mg
$ 624.00

Cayman Chemical
(+)-Goniothalesdiol ≥98%
1mg
$ 78.00

AK Scientific
(+)-Goniothalesdiol
10mg
$ 942.00

AK Scientific
(+)-Goniothalesdiol
5mg
$ 573.00

AK Scientific
(+)-Goniothalesdiol
1mg
$ 205.00

Total 5 raw suppliers

Chemical Property of Methyl 4,7-anhydro-2,3-dideoxy-7-phenylheptonate

Chemical Property:

Boiling Point:429.5±45.0 °C(Predicted)
PKA:13.59±0.70(Predicted)
Density:1.256±0.06 g/cm3(Predicted)
XLogP3:0.4
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:5
Exact Mass:266.11542367
Heavy Atom Count:19
Complexity:300

Purity/Quality:

99% ^*data from raw suppliers

(+)-Goniothalesdiol ≥98% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)CCC1C(C(C(O1)C2=CC=CC=C2)O)O

Technology Process of Methyl 4,7-anhydro-2,3-dideoxy-7-phenylheptonate

There total 20 articles about Methyl 4,7-anhydro-2,3-dideoxy-7-phenylheptonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 67-56-1
methanol

: 158673-96-2
(2R,3R,3aS,7aS)-tetrahydro-3-hydroxy-2-phenyl-2H-furo[3,2-b]pyran-5(6H)-one

: 204975-45-1
methyl 3-([2S,3S,4R,5R]-3,4-dihydroxy-5-phenyltetrahydrofuran-2-yl)propionate

Guidance literature:: With Amberlyst; at 20 ℃; for 10h;
DOI:10.1002/anie.200906830

Reference yield: 92.0%

: 1220627-90-6
methyl (4R,5S,6R,7R)-4-chloro-5,6,7-trihydroxy-7-phenylheptanoate

: 204975-45-1
methyl 3-([2S,3S,4R,5R]-3,4-dihydroxy-5-phenyltetrahydrofuran-2-yl)propionate

Guidance literature:: In methanol; at 120 ℃; for 1h; regioselective reaction; Microwave irradiation; Inert atmosphere;
DOI:10.1021/ol100260z

Reference yield: 75.0%

: 869733-37-9
methyl 3-[3,4-di-tert-butyldimethylsilanyloxy-5-phenyl-(2S,3R,4R,5R)-tetrahydro-2-furanyl]-propanoate

: 204975-45-1
methyl 3-([2S,3S,4R,5R]-3,4-dihydroxy-5-phenyltetrahydrofuran-2-yl)propionate

Guidance literature:: methyl 3-[3,4-di-tert-butyldimethylsilanyloxy-5-phenyl-(2S,3R,4R,5R)-tetrahydro-2-furanyl]-propanoate; With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 2h;

With amberlyst-15; In methanol; at 20 ℃; for 1h;
DOI:10.1021/jo060159f