(1R,5R,8R)-8-Methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl-hydroperoxide

Base Information

Chemical Name:(1R,5R,8R)-8-Methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl-hydroperoxide
CAS No.:779358-27-9
Molecular Formula:C₂₁H₂₄O₄S
Molecular Weight:372.485
Hs Code.:

Synonyms:(1R,5R,8R)-8-Methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl-hydroperoxide

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Chemical Property of (1R,5R,8R)-8-Methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl-hydroperoxide

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Technology Process of (1R,5R,8R)-8-Methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl-hydroperoxide

There total 4 articles about (1R,5R,8R)-8-Methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl-hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-98-5
thiophenol

: 779358-26-8
[1-((R)-4-Methyl-cyclohex-3-enyl)-vinyl]-benzene

: 779358-27-9
(1R,5R,8R)-8-Methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl-hydroperoxide

Guidance literature:: With 2,2'-azobis(isobutyronitrile); oxygen; In acetonitrile; at 0 ℃; for 0.5h; Irradiation;
DOI:10.1002/anie.200453859

Reference yield:

: 6090-09-1,57072-59-0,70286-20-3,54973-16-9
methyl-[(1R)-4-methylcyclohex-3-enyl]ketone

: 779358-27-9
(1R,5R,8R)-8-Methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl-hydroperoxide

Guidance literature:: Multi-step reaction with 3 steps

1: 64 percent / KHMDS / tetrahydrofuran / -78 - -40 °C

2: 75 percent / Ni(acac)2 / diethyl ether / 20 °C

3: O₂; azobis(isobutyronitrile) / acetonitrile / 0.5 h / 0 °C / Irradiation

With bis(acetylacetonate)nickel(II); 2,2'-azobis(isobutyronitrile); oxygen; potassium hexamethylsilazane; In tetrahydrofuran; diethyl ether; acetonitrile;
DOI:10.1002/anie.200453859

Reference yield:

: 4680-24-4
cis-(R)-limonene oxide

: 779358-27-9
(1R,5R,8R)-8-Methyl-4-phenyl-4-phenylsulfanylmethyl-2,3-dioxa-bicyclo[3.3.1]non-8-yl-hydroperoxide

Guidance literature:: Multi-step reaction with 4 steps

1.1: O₃ / CH₂Cl₂ / -78 °C

1.2: 50 percent / Zn; acetic acid; sodium iodide / sodium acetate

2.1: 64 percent / KHMDS / tetrahydrofuran / -78 - -40 °C

3.1: 75 percent / Ni(acac)2 / diethyl ether / 20 °C

4.1: O₂; azobis(isobutyronitrile) / acetonitrile / 0.5 h / 0 °C / Irradiation

With bis(acetylacetonate)nickel(II); 2,2'-azobis(isobutyronitrile); oxygen; potassium hexamethylsilazane; ozone; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1002/anie.200453859