trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

Base Information

Chemical Name:trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄
CAS No.:81654-88-8
Molecular Formula:BF₄*C₄₂H₅₆O₆P₅Ru
Molecular Weight:999.646
Hs Code.:

trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF<sub>4</sub>

Synonyms:trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

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Chemical Property of trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

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Technology Process of trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

There total 4 articles about trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 81624-51-3
RuH(η2-BH4)(bis(3-(diphenylphosphino)propyl)phenylphosphine)

: 121-45-9
phosphorous acid trimethyl ester

: 81654-88-8
trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

Guidance literature:: With CH₃CN; In tetrahydrofuran; 1 equiv of HBF4*(C2H5)2O added to a soln. of the Ru complex in THF and CH3CN, filtered, evapd., dissolved in acetone, P(OCH3)3 added; hexane added, crystals isolated the next day, washed with hexane, dried in vac.;
DOI:10.1021/om00078a001

Reference yield: 68.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 81624-51-3
RuHBH₄(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2)

: 121-45-9
phosphorous acid trimethyl ester

: 81654-88-8
trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

Guidance literature:: In tetrahydrofuran; to soln. of Ru-complex in THF was added P(OMe)3, stirred overnight, HBF4*Et2O was added at 25°C under N2; vol. was reduced, Et2O was added, oil was dissolved in acetone, dilutedwith hexane, filtered, dried in vac.; elem. anal.;
DOI:10.1021/ja00378a019

Reference yield: 27.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 81624-51-3
RuHBH₄(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2)

: 121-45-9
phosphorous acid trimethyl ester

: 81654-88-8
trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

: 81616-40-2
RuH(P(OCH₃)3)2(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2)⁽¹⁺⁾*BF₄^(1-)=RuH(P(OCH₃)3)2(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2)BF₄

Guidance literature:: In tetrahydrofuran; to soln. of Ru-complex in THF was added P(OMe)3, stirred for 10 min, HBF4*Et2O was added at 25°C under N2; vol. was reduced, Et2O was added, filtered, washed with ether, dried invac.; elem. anal.;
DOI:10.1021/ja00378a019