Benzenamine, 2,4-dimethoxy-, radical ion(1+) (9CI)

Base Information

• Chemical Name: Benzenamine, 2,4-dimethoxy-, radical ion(1+) (9CI)
• CAS No.: 161687-55-4
• Molecular Formula: C₈H₁₁NO₂
• Molecular Weight: 153.181
• Mol file: 161687-55-4.mol

Synonyms:Benzenamine, 2,4-dimethoxy-, radical ion(1+) (9CI)

Chemical Property of Benzenamine, 2,4-dimethoxy-, radical ion(1+) (9CI)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenamine, 2,4-dimethoxy-, radical ion(1+) (9CI)

There total 29 articles about Benzenamine, 2,4-dimethoxy-, radical ion(1+) (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2,4-dimethoxyphenylboronic acid (133730-34-4) → 2,4-Dimethoxyaniline (2735-04-8,161687-55-4)

Guidance literature:

With sodium hydroxide; hydroxylamine-O-sulfonic acid; In acetonitrile; at 20 ℃; for 16h;

DOI:10.1021/jo5025078

Reference yield: 94.0%

benzyl 2,4-dimethoxyphenylcarbamate (1137558-12-3) → 2,4-Dimethoxyaniline (2735-04-8,161687-55-4)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In ethyl acetate; for 6h; under 1551.49 Torr;

DOI:10.1021/jm801335z

Reference yield: 93.0%

2,4-dimethoxynitrobenzene (4920-84-7) → 2,4-Dimethoxyaniline (2735-04-8,161687-55-4)

Guidance literature:

With 2-pyrrolidinon; samarium diiodide; Reagent/catalyst; Glovebox;

DOI:10.1021/acs.orglett.6b03664

upstream raw materials:

(2,4-dimethoxy-phenyl)-phenyl-diazene

2,4-dimethoxynitrobenzene

N-(2,4-dimethoxyphenyl)acetamide

(3,4-dimethoxy-phenyl)-acetic acid-(2,4-dimethoxy-anilide)

Downstream raw materials:

(3,4-dimethoxy-phenyl)-acetic acid-(2,4-dimethoxy-anilide)

2-Methoxy-phenazin-10-oxid

6-methyl-[1,3]oxazinane-3-carboxylic acid (2,4-dimethoxy-phenylcarbamoyl)-amide

C₂₄H₂₅N₃O₄

Refernces

• 1、 -. "Methoxy aniline compound and synthesis method thereof". Paragraph 0027; 0030-0032; 0041-0042. . Retrieved 2021/05/19.
• 2、 Munnuri, Sailu,Anugu, Raghunath Reddy,Falck, John R.. "Cu(II)-Mediated N-H and N-Alkyl Aryl Amination and Olefin Aziridination". supporting information. p. 1926 - 1929. Retrieved 2019/03/11.