Acetic acid (E)-(2S,3S,4R,5R,6S,7R,10S)-10-[1,3]dithian-2-yl-2-hydroxy-3-methoxy-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-7-triisopropylsilanyloxy-undec-8-enyl ester

Base Information

Chemical Name:Acetic acid (E)-(2S,3S,4R,5R,6S,7R,10S)-10-[1,3]dithian-2-yl-2-hydroxy-3-methoxy-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-7-triisopropylsilanyloxy-undec-8-enyl ester
CAS No.:777096-54-5
Molecular Formula:C₃₈H₆₆O₇S₂Si
Molecular Weight:727.155
Hs Code.:

Acetic acid (E)-(2S,3S,4R,5R,6S,7R,10S)-10-[1,3]dithian-2-yl-2-hydroxy-3-methoxy-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-7-triisopropylsilanyloxy-undec-8-enyl ester

Synonyms:Acetic acid (E)-(2S,3S,4R,5R,6S,7R,10S)-10-[1,3]dithian-2-yl-2-hydroxy-3-methoxy-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-7-triisopropylsilanyloxy-undec-8-enyl ester

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Chemical Property of Acetic acid (E)-(2S,3S,4R,5R,6S,7R,10S)-10-[1,3]dithian-2-yl-2-hydroxy-3-methoxy-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-7-triisopropylsilanyloxy-undec-8-enyl ester

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Technology Process of Acetic acid (E)-(2S,3S,4R,5R,6S,7R,10S)-10-[1,3]dithian-2-yl-2-hydroxy-3-methoxy-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-7-triisopropylsilanyloxy-undec-8-enyl ester

There total 2 articles about Acetic acid (E)-(2S,3S,4R,5R,6S,7R,10S)-10-[1,3]dithian-2-yl-2-hydroxy-3-methoxy-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-7-triisopropylsilanyloxy-undec-8-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 251083-06-4
{(E)-(1R,4S)-1-[(1S,2R,3R,4S)-4-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-4-methoxy-2-(4-methoxy-benzyloxy)-1,3-dimethyl-butyl]-4-[1,3]dithian-2-yl-2-methyl-pent-2-enyloxy}-triisopropyl-silane

: 777096-54-5
Acetic acid (E)-(2S,3S,4R,5R,6S,7R,10S)-10-[1,3]dithian-2-yl-2-hydroxy-3-methoxy-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-7-triisopropylsilanyloxy-undec-8-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: PPTs / methanol

2: 2,4,6-collidine / -78 °C

With 2,4,6-trimethyl-pyridine; pyridinium p-toluenesulfonate; In methanol;
DOI:10.1021/ja0289649

Reference yield:

: 75-36-5
acetyl chloride

: 777096-29-4
(E)-(2S,3S,4R,5R,6S,7R,10S)-10-[1,3]Dithian-2-yl-3-methoxy-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-7-triisopropylsilanyloxy-undec-8-ene-1,2-diol

: 777096-54-5
Acetic acid (E)-(2S,3S,4R,5R,6S,7R,10S)-10-[1,3]dithian-2-yl-2-hydroxy-3-methoxy-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-7-triisopropylsilanyloxy-undec-8-enyl ester

Guidance literature:: With 2,4,6-trimethyl-pyridine; at -78 ℃;
DOI:10.1021/ja0289649

Reference yield:

: 777096-54-5
Acetic acid (E)-(2S,3S,4R,5R,6S,7R,10S)-10-[1,3]dithian-2-yl-2-hydroxy-3-methoxy-5-(4-methoxy-benzyloxy)-4,6,8-trimethyl-7-triisopropylsilanyloxy-undec-8-enyl ester

: 777096-56-7
C₆₈H₁₂₄O₁₀S₂Si₃

Guidance literature:: Multi-step reaction with 4 steps

1.1: TBAI; DIEA / CH₂Cl₂

2.1: K₂CO₃ / methanol

3.1: t-BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / 0.07 h / -78 °C

3.2: 75 percent / tetrahydrofuran / 0.17 h

4.1: SO₃*pyr; DMSO

With pyridine-SO₃ complex; tert.-butyl lithium; tetra-(n-butyl)ammonium iodide; potassium carbonate; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; 4.1: Parikh-Doering oxidation;
DOI:10.1021/ja0289649