[Fe(III)(tetraphenylporphyrin)(1-methylimidazole)(NO)]BF₄

Base Information

• Chemical Name: [Fe(III)(tetraphenylporphyrin)(1-methylimidazole)(NO)]BF₄
• CAS No.: 1081978-78-0
• Molecular Formula: BF₄*C₄₈H₃₄FeN₇O
• Molecular Weight: 867.496
• Mol file: 1081978-78-0.mol

Synonyms:[Fe(III)(tetraphenylporphyrin)(1-methylimidazole)(NO)]BF₄

Chemical Property of [Fe(III)(tetraphenylporphyrin)(1-methylimidazole)(NO)]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(III)(tetraphenylporphyrin)(1-methylimidazole)(NO)]BF₄

There total 1 articles about [Fe(III)(tetraphenylporphyrin)(1-methylimidazole)(NO)]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1-methyl-1H-imidazole (616-47-7) + 5,10,15,20-tetraphenylporphyrin iron(III) perchlorate (57715-43-2,59370-87-5) + nitrogen(II) oxide (10102-43-9) + potassium tetrafluoroborate (14075-53-7) → [Fe(III)(tetraphenylporphyrin)(1-methylimidazole)(NO)]BF4 (1081978-78-0)

Guidance literature:

In chloroform; mixt. of Fe complex and KBF4 in Schlenk flask purged with Ar, CHCl3 added, mixt. stirred at room temp. for 2 h, filtered, 1-methylimidazole added to filtrate, NO gas passed through soln. under stirring for 10 min; hexane slowly added, mixt. stored at -20°C for 2 d, ppt. filteredoff;

DOI:10.1021/ja801860u

upstream raw materials:

1-methyl-1H-imidazole

5,10,15,20-tetraphenylporphyrin iron(III) perchlorate

nitrogen(II) oxide

potassium tetrafluoroborate