bis[dichloro(μ-bis(diphenylphosphino)amine)molybdenum(II)]

Base Information

Chemical Name:bis[dichloro(μ-bis(diphenylphosphino)amine)molybdenum(II)]
CAS No.:105502-46-3
Molecular Formula:C₄₈H₄₂Cl₄Mo₂N₂P₄
Molecular Weight:1104.46
Hs Code.:

Synonyms:bis[dichloro(μ-bis(diphenylphosphino)amine)molybdenum(II)]

Suppliers and Price of bis[dichloro(μ-bis(diphenylphosphino)amine)molybdenum(II)]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of bis[dichloro(μ-bis(diphenylphosphino)amine)molybdenum(II)]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of bis[dichloro(μ-bis(diphenylphosphino)amine)molybdenum(II)]

There total 5 articles about bis[dichloro(μ-bis(diphenylphosphino)amine)molybdenum(II)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 75-77-4
chloro-trimethyl-silane

: 14221-06-8,744215-74-5
tetrakis(acetato)dimolybdenum(II)

: 2960-37-4
Bis(diphenylphosphanyl)amine

: 105502-46-3
bis[dichloro(μ-bis(diphenylphosphino)amine)molybdenum(II)]

Guidance literature:: In tetrahydrofuran; inert atmosphere; addn. of excess silane to mixt. of Mo-complex and 2 equiv. diphosphine at room temp., refluxing for 70 min (pptn.); can be recrystallized (layering CH2Cl2 soln. with hexanes, room temp., 5d);
DOI:10.1021/ic960325+

Reference yield: 61.0%

: 75-77-4
chloro-trimethyl-silane

: [Mo2(μ-O2CCH3)2Cl2(μ-bis(diphenylphosphino)amine)]

: 105502-46-3
bis[dichloro(μ-bis(diphenylphosphino)amine)molybdenum(II)]

Guidance literature:: In tetrahydrofuran; N2-atmosphere; stirring for 2 h (pptn.); collection (filtration), washing (ether), drying (reduced pressure);

Reference yield: 50.0%

: [Mo₂Cl₆(tetrahydrofuran)3]

: 109-89-7
diethylamine

: 2960-37-4
Bis(diphenylphosphanyl)amine

: 105502-46-3
bis[dichloro(μ-bis(diphenylphosphino)amine)molybdenum(II)]

Guidance literature:: With Na/Hg; In tetrahydrofuran; hexane; byproducts: NaCl; inert atmosphere; addn. of excess NHEt2 and 2 equiv. of 0.4% NaHg to Mo-complex soln. (in THF, -78°C), warming to room temp., stirring for 24 h, addn. of C6H6, filtration off of NaCl, addn. of excess phosphine(in hexanes), stirring for 90 min; evapn., washing (THF), dissoln. in hexanes, crystn. on layering with CH2Cl2;