methyl (7S)-3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)-ethyl]-β-D-glucopyranoside

Base Information

Chemical Name:methyl (7S)-3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)-ethyl]-β-D-glucopyranoside
CAS No.:1203550-48-4
Molecular Formula:C₃₂H₃₈O₇
Molecular Weight:534.65
Hs Code.:

Synonyms:methyl (7S)-3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)-ethyl]-β-D-glucopyranoside

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Chemical Property of methyl (7S)-3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)-ethyl]-β-D-glucopyranoside

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Technology Process of methyl (7S)-3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)-ethyl]-β-D-glucopyranoside

There total 6 articles about methyl (7S)-3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)-ethyl]-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 67-56-1
methanol

: 1203550-51-9
(3S,3aR,4R,5S,6R,7aR)-4,5-bis(benzyloxy)-6-benzyloxymethyl-3-methyl-2-oxohexahydrofuro[2,3-b]pyran

: 1203550-48-4
methyl (7S)-3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)-ethyl]-β-D-glucopyranoside

Guidance literature:: With scandium tris(trifluoromethanesulfonate); at 0 ℃; for 0.5h; Inert atmosphere;
DOI:10.1039/b918893m

Reference yield: 38.0%

: 1203550-47-3
methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[1,1-bis-(methoxycarbonyl)-ethyl]-β-D-glucopyranoside

: 1203550-48-4
methyl (7S)-3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)-ethyl]-β-D-glucopyranoside

: 1203550-49-5
methyl (7R)-3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)-ethyl]-β-D-glucopyranoside

Guidance literature:: With lithium iodide; In dimethyl sulfoxide; at 100 ℃; for 0.25h; under 7500.75 Torr; optical yield given as %de; Microwave irradiation;
DOI:10.1039/b918893m

Reference yield:

: 946512-99-8
methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside

: 74-88-4
methyl iodide

: 1203550-48-4
methyl (7S)-3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)-ethyl]-β-D-glucopyranoside

: 1203550-49-5
methyl (7R)-3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)-ethyl]-β-D-glucopyranoside

Guidance literature:: methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside; With lithium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 0.75h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; at -78 ℃; optical yield given as %de; stereoselective reaction; Inert atmosphere;
DOI:10.1039/b918893m