methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside

Base Information

Chemical Name:methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside
CAS No.:946512-99-8
Molecular Formula:C₃₁H₃₆O₇
Molecular Weight:520.623
Hs Code.:

Synonyms:methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside

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Chemical Property of methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside

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Technology Process of methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside

There total 3 articles about methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 67-56-1
methanol

: 1124225-72-4
(3aR,4R,5S,6R,7aR)-4,5-bis(benzyloxy)-6-benzyloxymethyl-2-oxohexahydrofuro[2,3-b]pyran

: 946512-99-8
methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside

Guidance literature:: (3aR,4R,5S,6R,7aR)-4,5-bis(benzyloxy)-6-benzyloxymethyl-2-oxohexahydrofuro[2,3-b]pyran; With calcium sulfate; scandium tris(trifluoromethanesulfonate); In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere;

methanol; In dichloromethane; at 0 - 20 ℃; stereoselective reaction; Inert atmosphere;
DOI:10.1002/chem.200802178

Reference yield: 92.0%

: 946512-97-6
methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(bis-methoxycarbonyl)methyl]-β-D-glucopyranoside

: 946512-99-8
methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside

Guidance literature:: With lithium iodide; In dimethyl sulfoxide; at 100 ℃; for 0.166667h; under 7500.75 Torr; microwave irradiation;
DOI:10.1039/b703358c

Reference yield:

: 55628-54-1
3,4,6-tri-O-benzyl-D-glucal

: 946512-99-8
methyl 3,4,6-tri-O-benzyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 78 percent / ceric(IV) ammonium nitrate; sodium hydrogen carbonate / methanol / 0.5 h / 0 °C

2: 92 percent / lithium iodide / dimethylsulfoxide / 0.17 h / 100 °C / 7500.75 Torr / microwave irradiation

With ammonium cerium(IV) nitrate; sodium hydrogencarbonate; lithium iodide; In methanol; dimethyl sulfoxide;
DOI:10.1039/b703358c