Welcome to LookChem.com Sign In|Join Free
  • or

Encyclopedia

Bromozinc(1+);ethylbenzene

Base Information Edit
  • Chemical Name:Bromozinc(1+);ethylbenzene
  • CAS No.:308796-14-7
  • Molecular Formula:C8H9BrZn
  • Molecular Weight:250.453
  • Hs Code.:
  • DSSTox Substance ID:DTXSID70410536
  • Mol file:308796-14-7.mol
Bromozinc(1+);ethylbenzene

Synonyms:bromozinc(1+);ethylbenzene;phenethylzinc bromide;DTXSID70410536

Suppliers and Price of Bromozinc(1+);ethylbenzene
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • Sigma-Aldrich
  • Phenethylzinc bromide solution 0.5 M in THF
  • 50ml
  • $ 385.00
  • Rieke Metals
  • Phenethylzincbromide
  • 50mL
  • $ 263.00
  • Matrix Scientific
  • Phenethylzincbromide 0.50MinTHF97%
  • 500ml
  • $ 1674.00
  • Matrix Scientific
  • Phenethylzincbromide 0.50MinTHF97%
  • 100ml
  • $ 646.00
  • Matrix Scientific
  • Phenethylzincbromide 0.50MinTHF97%
  • 50ml
  • $ 435.00
  • American Custom Chemicals Corporation
  • PHENETHYLZINC BROMIDE 95.00%
  • 1L
  • $ 7969.50
  • American Custom Chemicals Corporation
  • PHENETHYLZINC BROMIDE 95.00%
  • 500ML
  • $ 5313.00
  • American Custom Chemicals Corporation
  • PHENETHYLZINC BROMIDE 95.00%
  • 100ML
  • $ 2760.45
  • Alfa Aesar
  • 2-Phenylethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
  • 50ml
  • $ 170.00
Total 8 raw suppliers
Chemical Property of Bromozinc(1+);ethylbenzene Edit
Chemical Property:
  • Boiling Point:°Cat760mmHg 
  • Flash Point:°C 
  • PSA:0.00000 
  • Density:g/cm3 
  • LogP:3.03980 
  • Storage Temp.:2-8°C 
  • Sensitive.:Air Sensitive 
  • Water Solubility.:Reacts with water. 
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:1
  • Rotatable Bond Count:1
  • Exact Mass:247.91790
  • Heavy Atom Count:10
  • Complexity:53.1
Purity/Quality:

98%,99%, *data from raw suppliers

Phenethylzinc bromide solution 0.5 M in THF *data from reagent suppliers

Safty Information:
  • Pictogram(s):  
  • Hazard Codes:F,Xn 
  • Statements: 14-19-22-36/38-40-36/37-11 
  • Safety Statements: 16-26-33-36-36/37 
MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:
  • Canonical SMILES:[CH2-]CC1=CC=CC=C1.[Zn+]Br
  • Uses Phenethylzinc bromide can be used as a reagent: In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation. To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction. To synthesize benzyl substituted thienopyrimidine derivatives.
Technology Process of Bromozinc(1+);ethylbenzene

There total 2 articles about Bromozinc(1+);ethylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With iodine; In N,N-dimethyl acetamide; at 80 ℃; for 12h; Inert atmosphere;
DOI:10.1002/anie.201503297
Guidance literature:
ethylene dibromide; zinc; With lithium chloride; In tetrahydrofuran; at 85 ℃; for 0.5h; Inert atmosphere;
With chloro-trimethyl-silane; iodine; In tetrahydrofuran; for 0.333333h; Inert atmosphere; Reflux;
1-phenyl-2-bromoethane; In tetrahydrofuran; at 65 ℃; Inert atmosphere;
DOI:10.1021/acs.orglett.0c02515
Guidance literature:
2-(1-chloroethyl)naphthalene; 1-ethyl-2-isocyanobenzene; phenethylzinc(II) bromide; With tris-(dibenzylideneacetone)dipalladium(0); In N,N-dimethyl-formamide; at 60 ℃; for 2h; Schlenk technique; Inert atmosphere; Sealed tube;
With hydrogenchloride; water; In N,N-dimethyl-formamide; at 25 ℃; for 0.25h; Schlenk technique; Sealed tube; Inert atmosphere;
DOI:10.1021/acs.orglett.0c02515
Post RFQ for Price