Trimethylsilyl N,N-dimethylcarbamate

Base Information

• Chemical Name: Trimethylsilyl N,N-dimethylcarbamate
• CAS No.: 32115-55-2
• Molecular Formula: C6H15 N O2 Si
• Molecular Weight: 161.276
• Hs Code.: 2931900090
• European Community (EC) Number: 626-918-7
• DSSTox Substance ID: DTXSID30401763
• Nikkaji Number: J364.485E
• Mol file: 32115-55-2.mol

Synonyms:Trimethylsilyl N,N-dimethylcarbamate;32115-55-2;trimethylsilyl dimethylcarbamate;DMCTMS;SCHEMBL2692620;DTXSID30401763;N,N-Dimethyl-(trimethylsilyl)-carbamate;FT-0694051;Trimethylsilyl N,N-dimethylcarbamate, purum, >=95.0% (GC)

Chemical Property of Trimethylsilyl N,N-dimethylcarbamate

Chemical Property:

• Vapor Pressure: 11.7mmHg at 25°C
• Refractive Index: n20/D 1.418(lit.)
• Boiling Point: 74-75 °C20 mm Hg(lit.)
• PKA: -1.55±0.70(Predicted)
• Flash Point: 55 °F
• PSA: 29.54000
• Density: 0.925 g/mL at 25 °C(lit.)
• LogP: 1.51950
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 161.087205256
• Heavy Atom Count: 10
• Complexity: 128

Purity/Quality:

98%Min ^*data from raw suppliers

TRIMETHYLSILYL N,N-DIMETHYLCARBAMATE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 10
• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CN(C)C(=O)O[Si](C)(C)C

Technology Process of Trimethylsilyl N,N-dimethylcarbamate

There total 3 articles about Trimethylsilyl N,N-dimethylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

chloro-trimethyl-silane (75-77-4) + DIMCARB (4137-10-4) → N,N-Dimethylcarbamidsaeure-trimethylsilylester (32115-55-2)

Guidance literature:

In diethyl ether; for 2h;

Reference yield:

N,N-Dimethyltrimethylsilylamine (2083-91-2) + carbon dioxide (124-38-9,18923-20-1) → N,N-Dimethylcarbamidsaeure-trimethylsilylester (32115-55-2)

Guidance literature:

DOI:10.1021/ja00753a030

Reference yield:

→ N,N-Dimethylcarbamidsaeure-trimethylsilylester (32115-55-2)

Guidance literature:

Me2NC(O)OH-HNMe2, Me3SiCl;

DOI:10.1021/ja00734a022

upstream raw materials:

N,N-Dimethyltrimethylsilylamine

carbon dioxide

chloro-trimethyl-silane

DIMCARB

Downstream raw materials:

trimethylsilyl acetate

N,N-dimethyl acetamide

phenyltrimethylsilyl ether

phenyl N,N-dimethylcarbamate

Refernces

• 1、 Smith, Catherine J.,Tsang, Melanie W.S.,Holmes, Andrew B.,Danheiser, Rick L.,Tester, Jefferson W.. "Palladium catalysed aryl amination reactions in supercritical carbon dioxide". . p. 3767 - 3781. Retrieved 2007/10/03.
• 2、 Knausz, Dezsoe,Meszticzky, Aranka,Szakacs, Laszlo,Csakvari, Bela,Ujszaszy, Kalman. "TRIMETHYLSILYLATED N-ALKYL-SUBSTITUTED CARBAMATES. I. PREPARATION AND SOME REACTIONS". . p. 11 - 22. Retrieved 2007/10/02.