Cp*IrCl(η3-CH2CHCHPh)

Base Information

Chemical Name:Cp*IrCl(η3-CH2CHCHPh)
CAS No.:260783-56-0
Molecular Formula:C₁₉H₂₄ClIr
Molecular Weight:480.073
Hs Code.:

Synonyms:Cp*IrCl(η3-CH2CHCHPh)

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Chemical Property of Cp*IrCl(η3-CH2CHCHPh)

Chemical Property:

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Technology Process of Cp*IrCl(η3-CH2CHCHPh)

There total 11 articles about Cp*IrCl(η3-CH2CHCHPh) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 56-23-5
tetrachloromethane

: 191666-77-0
[Cp(*)Ir(η(3)-CHPhCHCH2)(NCMe)](OTf)

: 75-50-3
trimethylamine

: 260783-56-0
Cp*IrCl(η3-CH2CHCHPh)

: 260783-84-4
[Me₃NCCl₃]OTf

Guidance literature:: In tetrachloromethane; NMe3 was added to CCl4 soln. (Cp*Ir(η3-CH2CHCHPh)(NCMe))OTf and react. mixt. was refluxed for 2.5 h; volatiles were removed by vac. distillation, n-pentane was added, react. mixt. was filtered, solvent was distilled off under vac. from filtrate, residuewas recrystd. from n-pentane/MeOH at -20°C; elem. anal.;
DOI:10.1021/om9908480

Reference yield: 98.0%

: 191666-77-0
[Cp(*)Ir(η(3)-CHPhCHCH2)(NCMe)](OTf)

: 100-44-7
benzyl chloride

: 121-44-8
triethylamine

: benzyltriethylammonium trifluoromethanesulfonate

: 260783-56-0
Cp*IrCl(η3-CH2CHCHPh)

Guidance literature:: In further solvent(s); NEt3 was added to PhCH2Cl soln. (Cp*Ir(η3-CH2CHCHPh)(NCMe))OTf and react. mixt. was refluxed for 2.5 h; volatiles were removed by vac. distillation, n-pentane was added, react. mixt. was filtered, solvent was distilled off under vac. from filtrate, residuewas recrystd. from n-pentane/MeOH at -20°C; elem. anal.;
DOI:10.1021/om9908480

Reference yield: 97.0%

: 191666-77-0
[Cp(*)Ir(η(3)-CHPhCHCH2)(NCMe)](OTf)

: 100-44-7
benzyl chloride

: 75-50-3
trimethylamine

: 260783-56-0
Cp*IrCl(η3-CH2CHCHPh)

: 260783-80-0
N,N,N--trimethyl--1--phenylmethanaminium trifluoromethanesulfonate

Guidance literature:: In further solvent(s); NMe3 was added to PhCH2Cl soln. (Cp*Ir(η3-CH2CHCHPh)(NCMe))OTf and react. mixt. was refluxed for 2.5 h; volatiles were removed by vac. distillation, n-pentane was added, react. mixt. was filtered, solvent was distilled off under vac. from filtrate, residuewas recrystd. from n-pentane/MeOH at -20°C; elem. anal.;
DOI:10.1021/om9908480