7-(tert-butoxy)-5-methoxy-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole

Base Information

Chemical Name:7-(tert-butoxy)-5-methoxy-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole
CAS No.:1269631-74-4
Molecular Formula:C₄₂H₄₂N₂O₅
Molecular Weight:654.806
Hs Code.:

Synonyms:7-(tert-butoxy)-5-methoxy-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole

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Chemical Property of 7-(tert-butoxy)-5-methoxy-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole

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Technology Process of 7-(tert-butoxy)-5-methoxy-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole

There total 25 articles about 7-(tert-butoxy)-5-methoxy-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 5-bromo-7-(tert-butoxy)-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole

: 124-41-4
sodium methylate

: 1269631-74-4
7-(tert-butoxy)-5-methoxy-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole

Guidance literature:: With copper(l) iodide; In methanol; N,N-dimethyl-formamide; at 80 ℃; for 11h; Inert atmosphere;
DOI:10.1002/anie.201703279

Reference yield:

: 7-(tert-butoxy)-4-(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole

: 1269631-74-4
7-(tert-butoxy)-5-methoxy-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole

Guidance literature:: Multi-step reaction with 5 steps

1.1: N-Bromosuccinimide / tetrahydrofuran / 1 h / 0 °C

1.2: 60 h / 0 - 20 °C

2.1: potassium phosphate; bis(tri-t-butylphosphine)palladium⁽⁰⁾ / water; 1,4-dioxane / 14 h / 80 °C / Inert atmosphere

3.1: N-Bromosuccinimide / tetrahydrofuran / 3.75 h / -78 - 20 °C / Inert atmosphere

4.1: palladium diacetate; N,N,N,N,-tetramethylethylenediamine; sodium tetrahydroborate; triphenylphosphine / tetrahydrofuran / 3 h / 40 °C / Inert atmosphere

5.1: copper(l) iodide / methanol; N,N-dimethyl-formamide / 11 h / 80 °C / Inert atmosphere

With sodium tetrahydroborate; potassium phosphate; N-Bromosuccinimide; copper(l) iodide; bis(tri-t-butylphosphine)palladium⁽⁰⁾; N,N,N,N,-tetramethylethylenediamine; palladium diacetate; triphenylphosphine; In tetrahydrofuran; 1,4-dioxane; methanol; water; N,N-dimethyl-formamide; 2.1: |Suzuki-Miyaura Coupling;
DOI:10.1002/anie.201703279

Reference yield:

: 14425-64-0
4-methoxyphenethyl bromide

: 1269631-74-4
7-(tert-butoxy)-5-methoxy-3-(4-methoxyphenethyl)-1,4-bis(4-methoxyphenyl)-3,6-dihydropyrrolo[2,3-c]carbazole

Guidance literature:: Multi-step reaction with 4 steps

1.1: potassium hydroxide / N,N-dimethyl-formamide / 0.17 h / 20 °C

1.2: 2 h

2.1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium acetate / 1,4-dioxane / 1.5 h / Reflux

3.1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; sodium hydroxide / 1,4-dioxane; water / 1.5 h / 20 °C

4.1: 1,2-dichloro-benzene / 0.5 h / Inert atmosphere; Reflux

With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium acetate; potassium hydroxide; sodium hydroxide; In 1,4-dioxane; water; N,N-dimethyl-formamide; 1,2-dichloro-benzene; 3.1: Suzuki-Miyaura coupling;
DOI:10.1002/asia.201000544