Technology Process of hydrogencarbonatobis(triphenylphosphine)copper(I)
There total 4 articles about hydrogencarbonatobis(triphenylphosphine)copper(I) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
carbon dioxide; water; phenol;
In
tetrahydrofuran;
under N2, water added to THF soln. of Cu complex and phenol, CO2 bubbled into soln. for 5 min at -10 to 0°C; ppt. washed repeatedly with diethyl ether, dried in vac., elem. anal.;
DOI:10.1246/bcsj.53.680
- Guidance literature:
-
In
water; acetonitrile;
a soln. of Cu-contg. compd. (1.0 mmol) in CH3CN at ambient temp. was slowly added dropwise to a stirred soln. of NaHCO3 (25.4 mmol) in H2O at ambient temp.; the ppt. was collected and washed with H2O and a small vol. of EtOH; elem. anal.;
DOI:10.1039/c1dt10416k
- Guidance literature:
-
With
triphenylphosphine; carbon dioxide;
In
toluene;
addn. of triphenylphosphine to stirred suspn. of Cu-compd. under dry nitrogen at 0°C, the deep-orange soln. formed was filtered and CO2 bubbled through it for a few hours, HOCO2Cu(PPh3)2 sepd. spontaneously from soln.; o-TCO2Cu(PPh3)2 pptd. by adding ether to the previously concd. soln., elem. anal.;
DOI:10.1016/S0022-328X(00)95267-7
