α-Azidobenzyl Phenyl Sulfide

Base Information

• Chemical Name: α-Azidobenzyl Phenyl Sulfide
• CAS No.: 70891-83-7
• Molecular Formula: C₁₃H₁₁N₃S
• Molecular Weight: 241.316
• Mol file: 70891-83-7.mol

Synonyms:α-Azidobenzyl Phenyl Sulfide

Chemical Property of α-Azidobenzyl Phenyl Sulfide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of α-Azidobenzyl Phenyl Sulfide

There total 1 articles about α-Azidobenzyl Phenyl Sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Benzyl phenyl sulfide (831-91-4) → α-Azidobenzyl Phenyl Sulfide (70891-83-7)

Guidance literature:

With sodium azide; sulfuryl dichloride; Yield given. Multistep reaction; 1.) CCl4, 75 min, 2.) DMSO-DMF, <25 deg C, 1 h;

DOI:10.1021/jo01299a050

Reference yield: 74.0%

α-Azidobenzyl Phenyl Sulfide (70891-83-7) → N-benzylidene-S-phenylthiohydroxylamine (52777-99-8) + benzaldehyde (100-52-7) + benzonitrile (100-47-0) + diphenyldisulfane (882-33-7)

Guidance literature:

In diphenylether; at 120 ℃; for 3h; Mechanism; Rate constant; Thermodynamic data; Arrenius parameters (ΔH(excit.), ΔS(excit.)); further temperatures; further solvents;

DOI:10.1021/ja00403a043

Reference yield: 65.0%

α-Azidobenzyl Phenyl Sulfide (70891-83-7) → α-Azidobenzyl Phenyl Sulfone (70891-93-9)

Guidance literature:

With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; water; at 0 - 10 ℃; for 1h;

DOI:10.1021/jo01299a050

upstream raw materials:

Benzyl phenyl sulfide

Downstream raw materials:

α-Azidobenzyl Phenyl Sulfone

N-benzylidene-S-phenylthiohydroxylamine

benzaldehyde

benzonitrile

Refernces