Sodium formate-d

Base Information

• Chemical Name: Sodium formate-d
• CAS No.: 3996-15-4
• Molecular Formula: CDNaO2
• Molecular Weight: 68.9996
• Hs Code.: 28459000
• European Community (EC) Number: 622-208-6
• DSSTox Substance ID: DTXSID40583625
• Nikkaji Number: J2.109.175H
• Mol file: 3996-15-4.mol

Synonyms:Sodium formate-d;3996-15-4;SODIUM FORMATE-D1;Formic-d acid sodium salt;Sodium;deuterioformate;MFCD00075589;SODIUMFORMATE-D1;Sodium (~2~H)formate;Formic-D acid,sodium salt;DTXSID40583625;Sodium formate-d, 99 atom % D;HY-W088065S2;CS-0542325;D97993

Chemical Property of Sodium formate-d

Chemical Property:

• Melting Point: 259-262 °C(lit.)
• PSA: 40.13000
• LogP: -0.99800
• Storage Temp.: Refrigerator
• Solubility.: Water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 68.99370030
• Heavy Atom Count: 4
• Complexity: 13.5

Purity/Quality:

99% ^*data from raw suppliers

Sodium Formate-d ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)[O-].[Na+]
• Isomeric SMILES: [2H]C(=O)[O-].[Na+]
• Uses: SODIUM FORMATE-D1 is used in various organic reactions and syntheses. It is used in the preparation of [3,2b]pyridines as well as the palladium-catalyzed coupling of vinyl triflates with organos tannanes.

Technology Process of Sodium formate-d

There total 1 articles about Sodium formate-d which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

sodium cyanide (773837-37-9) + water-d2 (7789-20-0) → sodium formate (3996-15-4) + ammonia-d3 (13550-49-7)

Guidance literature:

With sodium hydroxide; In water-d2; a mixt. of NaCN, NaOH and D2O was refluxed for 2 wk; distd., the residue was dissolved in H2O, HCl to pH 8.0 was added;

DOI:10.1021/ja00353a026

Reference yield: 87.0%

sodium formate (3996-15-4) + benzyl bromide (100-39-0) → benzyl formate-d

Guidance literature:

In N,N,N,N,N,N-hexamethylphosphoric triamide; for 60h; Ambient temperature;

DOI:10.1021/ja00125a010

Reference yield: 86.0%

N-benzyl-3-butenylamine (17150-62-8) + sodium formate (3996-15-4) → N-benzyl-N-(but-3-en-1-yl)formamide-d (1449219-05-9)

Guidance literature:

N-benzyl-3-butenylamine; sodium formate; With triethylamine hydrochloride; In dichloromethane; at 23 ℃; for 0.5h; Inert atmosphere;

With dicyclohexyl-carbodiimide; In dichloromethane; at 23 ℃; for 16h; Inert atmosphere;

DOI:10.1021/ja406730t

upstream raw materials:

sodium cyanide

water-d2

Downstream raw materials:

sodium formate

dideuterioformic acid

water-d2

N-benzyl-N-(but-3-en-1-yl)formamide-d