Ammonia-d3

Base Information

• Chemical Name: Ammonia-d3
• CAS No.: 13550-49-7
• Molecular Formula: D3N
• Molecular Weight: 20.0067
• European Community (EC) Number: 236-926-9
• DSSTox Substance ID: DTXSID80159429
• Nikkaji Number: J96.058F
• Wikidata: Q83027758
• Mol file: 13550-49-7.mol

Synonyms:Ammonia-d3;13550-49-7;(2H3)Ammonia;EINECS 236-926-9;84796-14-5;Ammonia-d3-;Ammonia-d3 (gas);Ammonia-d3, 99 atom % D;D3-N;DTXSID80159429;MFCD00051052;AKOS015903817;D3N

Chemical Property of Ammonia-d3

Chemical Property:

• Appearance/Colour: Colorless
• Vapor Pressure: 4802 mm Hg ( 15.5 °C)
• Melting Point: -78 °C(lit.)
• Boiling Point: -33 °C(lit.)
• Flash Point: 132 °C
• PSA: 3.24000
• Density: 0.6 (vs air)(vapor density )
• LogP: 0.32390
• Storage Temp.: -20°C
• XLogP3: -0.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 20.045379338
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Ammonium-d4 deuteroxide solution 25?wt. % in D2O, 99 atom % D ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T; C; N
• Hazard Codes: T,N,C
• Statements: 10-23-34-50
• Safety Statements: 9-16-26-36/37/39-45-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: N
• Isomeric SMILES: [2H]N([2H])[2H]

Technology Process of Ammonia-d3

There total 25 articles about Ammonia-d3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

sodium cyanide (773837-37-9) + water-d2 (7789-20-0) → sodium formate (3996-15-4) + ammonia-d3 (13550-49-7)

Guidance literature:

With sodium hydroxide; In water-d2; a mixt. of NaCN, NaOH and D2O was refluxed for 2 wk; distd., the residue was dissolved in H2O, HCl to pH 8.0 was added;

DOI:10.1021/ja00353a026

Reference yield:

nitrogen(II) oxide (10102-43-9) + deuterium (16873-17-9,12184-84-8) → nitrogen (7727-37-9) + ammonia-d3 (13550-49-7) + dinitrogen monoxide (10024-97-2)

Guidance literature:

Pt⁽²⁵⁾,Rh⁽⁷⁵⁾ (A%); In neat (no solvent, gas phase); investigation of NO redn. with H2 over a Pt0.25Rh0.75(100) alloy surface under steady-state conditions 400-800 K (D2 pressure from 1E-7 to 6E-6 mbar, 1.2E-7 mbar NO pressure); react. is monitored by mass spectroscopy;; Kinetics;

DOI:10.1016/0039-6028(92)90463-G

Reference yield:

4.5(2)H3N*INa → ammonia-d3 (13550-49-7) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6)

Guidance literature:

In neat (no solvent); decomposition; decomposition pressure in dependence on temperature discussed;;

upstream raw materials:

deuterium

nitrogen(II) oxide

ammonia

water-d2

Downstream raw materials:

nitrogen

dinitrogen monoxide

deuterium

Refernces

• 1、 Taylor, H. S.,Jungers, J. C.. "". . p. 660. Retrieved 1935.
• 2、 Wijekoon,Koenig,Hetherington III,Salzman. "Direct observation of the symmetric bending vibrations (ν2) of NH3 physisorbed on a partially hydroxylated planar (0001) surface of ZnO". . p. L929 - L934,L929-L934. Retrieved 1993.
• 3、 Broenstrup, Mark,Schroeder, Detlef,Kretzschmar, Ilona,Schalley, Christoph A.,Schwarz, Helmut. "Mass-spectrometric experiments together with electronic structure calculations support the existence of the elusive ammonia oxide molecule and its radical cation". . p. 1529 - 1538. Retrieved 1998.
• 4、 Lewis, G. N.. "". . p. 3502. Retrieved 1933.
• 5、 Nwalor, John U.,Goodwin, James G. Jr.,Biloen, Paul. "". . p. 121 - 134. Retrieved 1989.
• 6、 Neumann, D. A.,Zabel, H.,Fan, Y. B.,Solin, S. A.,Rush, J. J.. "". . . Retrieved 1988.
• 7、 Taylor, H. S.,Jungers, J. C.. "". . p. 452. Retrieved 1934.
• 8、 Kendall, Alexander J.,Johnson, Samantha I.,Bullock, R. Morris,Mock, Michael T.. "Catalytic Silylation of N2 and Synthesis of NH3 and N2H4 by Net Hydrogen Atom Transfer Reactions Using a Chromium P4 Macrocycle". supporting information. p. 2528 - 2536. Retrieved 2018/02/28.