(4-trifluoromethylbenzoyl)ferrocene

Base Information

Chemical Name:(4-trifluoromethylbenzoyl)ferrocene
CAS No.:72848-08-9
Molecular Formula:C₁₈H₁₃F₃FeO
Molecular Weight:358.143
Hs Code.:

Synonyms:(4-trifluoromethylbenzoyl)ferrocene

Suppliers and Price of (4-trifluoromethylbenzoyl)ferrocene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (4-trifluoromethylbenzoyl)ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (4-trifluoromethylbenzoyl)ferrocene

There total 1 articles about (4-trifluoromethylbenzoyl)ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 102-54-5,55404-68-7
ferrocene

: 329-15-7
4-trifluoromethyl-phenyl acetyl chloride

: 72848-08-9
(4-trifluoromethylbenzoyl)ferrocene

Guidance literature:: With aluminum (III) chloride; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.joc.5b01548

Reference yield: 99.0%

: 72848-08-9
(4-trifluoromethylbenzoyl)ferrocene

: 5470-11-1
hydroxylamine hydrochloride

: 75183-07-2
(C₅H₅)Fe(C₅H₄C(C₆H₄CF₃)NOH)

Guidance literature:: In pyridine; standing of a soln. of ferrocene-compd. and hydroxylamine hydrochloridein dry pyridine at room temp. for 24 h under N2; pouring into water, pptn., recrystn. from MeOH;

Reference yield: 80.0%

: 72848-08-9
(4-trifluoromethylbenzoyl)ferrocene

: 124-40-3
dimethyl amine

: 75183-25-4
(C₅H₅)Fe(C₅H₄C(C₆H₄CF₃)N(CH₃)2)⁽¹⁺⁾*PF₆^(1-)=(C₅H₅)Fe(C₅H₄C(C₆H₄CF₃)N(CH₃)2)PF₆

Guidance literature:: With aluminium chloride dimer; In 1,2-dichloro-ethane; slow addn. of amine to a stirred suspn. of finely powdered Al2Cl6 in dry ClCH2CH2Cl, stirring until complex formation is complete, addn. of aroylferrocene in ClCH2CH2Cl, stirring and heating to 90°C for 6 h under N2; pouring into water, sepn. of aq. layer, washing with ether, addn. of NH4PF6, extn. with CH2Cl2, drying extract (MgSO4), evapn. to low bulk under reduced pressure, pptn. by addn. of light petroleum, recrystn. from ether/CH2Cl2;