(μ,η2-PhCO)(μ-Me3CS)Fe2(CO)6

Base Information

Chemical Name:(μ,η2-PhCO)(μ-Me3CS)Fe2(CO)6
CAS No.:118013-31-3
Molecular Formula:C₁₇H₁₄Fe₂O₇S
Molecular Weight:474.054
Hs Code.:

Synonyms:(μ,η2-PhCO)(μ-Me3CS)Fe2(CO)6

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Chemical Property of (μ,η2-PhCO)(μ-Me3CS)Fe2(CO)6

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Technology Process of (μ,η2-PhCO)(μ-Me3CS)Fe2(CO)6

There total 3 articles about (μ,η2-PhCO)(μ-Me3CS)Fe2(CO)6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 17685-52-8
triiron dodecarbonyl

: 1192-89-8
bromo(phenyl)mercury

: 75-66-1
2-methylpropan-2-thiol

: 118013-31-3
(μ,η2-PhCO)(μ-Me3CS)Fe2(CO)6

Guidance literature:: With triethylamine; In tetrahydrofuran; addn. of thiol and Et3N to Fe3(CO)12 soln. (equim. amts., room temp., N2-atmosphere), addn. of Hg-compd., stirring (3 h); chromy. (SiO2, pentane);

Reference yield: 86.0%

: 17685-52-8
triiron dodecarbonyl

: 1192-89-8
bromo(phenyl)mercury

: 75-66-1
2-methylpropan-2-thiol

: 118013-31-3
(μ,η2-PhCO)(μ-Me3CS)Fe2(CO)6

: bis(μ-tert-butylsulphido)hexacarbonyldiiron

Guidance literature:: With (C₂H₅)3N; In tetrahydrofuran; byproducts: Hg, CO, (C2H5)3NHBr; (N2); Fe3(CO)12, t-BuSH and Et3N stirred at room temp. for 30 min; PhHgCl added, stirred at room temp. overnight; filtered, solvent removed in vacuo; extd. (pentane/CH2Cl2=80/20); filtration chromy. (silicic acid pad, pentane);

Reference yield:

: 17685-52-8
triiron dodecarbonyl

: 98-88-4
benzoyl chloride

: 75-66-1
2-methylpropan-2-thiol

: 121-44-8
triethylamine

: 118013-31-3
(μ,η2-PhCO)(μ-Me3CS)Fe2(CO)6

Guidance literature:: In tetrahydrofuran; reaction carried out under N2; (CH3)3CSH and (C2H5)3N added to soln. of Fe3(CO)12 in THF, stirred (15 min.),benzoylchloride added, stirred (20h), dark red soln. with white ppt., filtered, solvent removed, red oil dissolved in pentane; extd., filtered, filtration chromy. (silicic acid/pentane); recrystd. at -20°C; elem. anal.; yield of isomer mixt. 70%;