1,4-DI(DODECYLOXY)BENZENE

Base Information

• Chemical Name: 1,4-DI(DODECYLOXY)BENZENE
• CAS No.: 3230-09-9
• Molecular Formula: C30H54 O2
• Molecular Weight: 446.758
• Hs Code.: 2909309090
• Mol file: 3230-09-9.mol

Synonyms:Benzene,p-bis(dodecyloxy)- (7CI,8CI); 1,4-Bis(dodecanoxy)benzene;1,4-Bis(dodecyloxy)benzene; 1,4-Didodecanoxybenzene; 1,4-Didodecyloxybenzene;1,4-Dilauryloxybenzene; Hydroquinone didodecyl ether

Chemical Property of 1,4-DI(DODECYLOXY)BENZENE

Chemical Property:

• PSA: 18.46000
• LogP: 10.28600

Purity/Quality:

99% ^*data from raw suppliers

1,4-BIS-(DODECYLOXY)BENZENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,4-DI(DODECYLOXY)BENZENE

There total 8 articles about 1,4-DI(DODECYLOXY)BENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1-dodecylbromide (143-15-7) + hydroquinone (123-31-9,8027-02-9) → 1,4-bis-dodecyloxy-benzene (3230-09-9)

Guidance literature:

With potassium carbonate; potassium iodide; In N,N-dimethyl-formamide; at 20 - 80 ℃; for 64h;

DOI:10.1002/chem.201203444

Reference yield: 10.7%

hydroquinone (123-31-9,8027-02-9) + 1-chlorododecane (112-52-7) → 1,4-bis-dodecyloxy-benzene (3230-09-9)

Guidance literature:

hydroquinone; With potassium carbonate; In N,N-dimethyl-formamide; for 0.333333h; Inert atmosphere;

1-chlorododecane; In N,N-dimethyl-formamide; at 80 ℃; for 35h; Inert atmosphere;

DOI:10.1039/c9cc08541f

Reference yield:

sodium dodecyl-sulfate (151-21-3) + sodium 4-hydroxybenzen-1-olate (30008-10-7) → 4-dodecyloxyphenol (13037-87-1) + 1,4-bis-dodecyloxy-benzene (3230-09-9)

Guidance literature:

With hydroquinone; at 160 ℃;

upstream raw materials:

dodecyl 4-methylbenzenesulphonate

sodium 4-hydroxybenzen-1-olate

sodium dodecyl-sulfate

1-dodecylbromide

Downstream raw materials:

2,5-bis(dodecyloxy)bromobenzene

1,4-bis(bromomethyl)-2,5-bis-(dodecyloxy)benzene

dimethyl 4,4'-((2,5-bis(dodecyloxy)-1,4-phenylene)bis(ethyne-2,1-diyl))dibenzoate

4,4'-((2,5-bis(dodecyloxy)-1,4-phenylene)bis(ethyne-2,1-diyl))dibenzoic acid

Refernces

• 1、 Nikookar, Hamideh,Rashidi-Ranjbar, Parviz. "A photoluminescent molecular host with aggregation-induced emission enhancement, multi-stimuli responsive properties and tunable photoluminescence host-guest interaction in the solid state". . . Retrieved 2019/10/05.
• 2、 -. "Bipyridyl ligand and preparation method thereof, ruthenium supramolecular self-assembly body containing bipyridyl ligand and preparation method and application of ruthenium supramolecular self-assembly". Paragraph 0030-0036. . Retrieved 2020/08/18.