2-pyridin-2-ylpyridine; ruthenium(+3) cation

Base Information

• Chemical Name: 2-pyridin-2-ylpyridine; ruthenium(+3) cation
• CAS No.: 18955-01-6
• Molecular Formula: C₃₀H₂₄N₆Ru
• Molecular Weight: 569.631
• Mol file: 18955-01-6.mol

Synonyms:

Chemical Property of 2-pyridin-2-ylpyridine; ruthenium(+3) cation

Chemical Property:

• Boiling Point: 272.5°Cat760mmHg
• Flash Point: 107.2°C
• Density: g/cm³

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-pyridin-2-ylpyridine; ruthenium(+3) cation

There total 10 articles about 2-pyridin-2-ylpyridine; ruthenium(+3) cation which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(bipyridine)ruthenium(II) dichloride hexahydrate + water (7732-18-5) → tris-2,2'-bipyridyl ruthenium(III) ion (18955-01-6,104759-03-7,24162-13-8) + hydrogen (1333-74-0)

Guidance literature:

With disodium ethylenediaminetetraacetic acid; paraquat; platinum; In not given; Irradiation (UV/VIS); soln. of complex, Na2EDTA, electron-trasfer mediator, polyvinyl stabilized Pt catalyst, buffer (phosphate or borate) irradiated for 4-6 h at 23°C, various pH; hydrogen measured by chromy.; Kinetics;

DOI:10.1021/ic50217a065

Reference yield:

tris(2,2’-bipyridine)ruthenium(II) (52389-25-0,24162-12-7,15158-62-0) → tris-2,2'-bipyridyl ruthenium(III) ion (18955-01-6,104759-03-7,24162-13-8) + hydrogen (1333-74-0)

Guidance literature:

With water; In water; Irradiation (UV/VIS); under Ar; laser flash photolysis; bufferred to pH5 with acetic acid/acetate; system- Ru(bipy)3(2+)/electron transfer relay/EDTA/colloidal Pt; Kinetics;

Reference yield:

dichlorine radical anion + tris(2,2'-bipyridine)ruthenium(II) chloride pentahydrate → tris-2,2'-bipyridyl ruthenium(III) ion (18955-01-6,104759-03-7,24162-13-8) + chloride (16887-00-6)

Guidance literature:

With lithium chloride; dinitrogen monoxide; In hydrogenchloride; other Radiation; continuous irradiation ((60)Co) of a N2O-saturated solution containing 8.0 M LiCl, 1.0 mM HCl and 0.11 mM Ru(II) compound; Cl2(1-) radicals were formed during radiolysis; mechanism discussed;; not isolated; detected by UV spectroscopy;; Kinetics;

upstream raw materials:

dinitrogen monoxide

tris(2,2’-bipyridine)ruthenium(II)

water

oxygen

Downstream raw materials:

phosphonic Acid

tris(2,2’-bipyridine)ruthenium(II)

mercury ion

1-Chloropropane