3-(N-benzoylamino)-1,2-dicarba-closo-dodecaborane

Base Information

Chemical Name:3-(N-benzoylamino)-1,2-dicarba-closo-dodecaborane
CAS No.:22043-75-0
Molecular Formula:C₉H₁₇B₁₀NO
Molecular Weight:263.35
Hs Code.:

Synonyms:3-(N-benzoylamino)-1,2-dicarba-closo-dodecaborane

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Chemical Property of 3-(N-benzoylamino)-1,2-dicarba-closo-dodecaborane

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Technology Process of 3-(N-benzoylamino)-1,2-dicarba-closo-dodecaborane

There total 6 articles about 3-(N-benzoylamino)-1,2-dicarba-closo-dodecaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 22043-65-8
3-amino-1,2-dicarbaborane

: 98-88-4
benzoyl chloride

: 22043-75-0
3-(N-benzoylamino)-1,2-dicarba-closo-dodecaborane

Guidance literature:: With pyridine; In dichloromethane; Ar-atmosphere; addn. of PhCOCl, excess pyridine and catalyst to carborane, stirring for 2 h at room temp.; solvent removal, dissoln. in EtOAc, washing (satd. aq. NaHCO3, water), passing over SiO2;

Reference yield: 90.0%

: 137495-63-7
3-iodo-1,2-dicarba-closo-dodecaborane

: 55-21-0,27208-38-4
benzamide

: 22043-75-0
3-(N-benzoylamino)-1,2-dicarba-closo-dodecaborane

Guidance literature:: With K₃PO₄; 2-Cy₂P-2-(N,N-dimethylamino)biphenyl; tris(dibenzylideneacetone)dipalladium; In toluene; (Ar); toluene was added to mixt. of carborane, amide, K3PO4, 2-dicyclohexylphosphino-2-(N,N-dimethylamino)biphenyl and Pd2(dba)3, heated at 100°C for 2 h; filtered, , evapd., column chromy. (silica, CH2Cl2-hexane, from 0:100, concentration of CH2Cl2 was continiously increased), passed through active carbon column or crystd. from Et2O/hexane and CH2Cl2/hexane;
DOI:10.1021/ic101620h