3,4,6-tri-O-acetyl-2'<(2R)-2-benzyloxytridecyl>-1,2-dideoxy-5'6'-dyhydro-α-D-glucopyranoso<2,1-d>oxazole

Base Information

• Chemical Name: 3,4,6-tri-O-acetyl-2'<(2R)-2-benzyloxytridecyl>-1,2-dideoxy-5'6'-dyhydro-α-D-glucopyranoso<2,1-d>oxazole
• CAS No.: 96236-89-4
• Molecular Formula: C₃₃H₄₉NO₉
• Molecular Weight: 603.753
• Mol file: 96236-89-4.mol

Synonyms:3,4,6-tri-O-acetyl-2'<(2R)-2-benzyloxytridecyl>-1,2-dideoxy-5'6'-dyhydro-α-D-glucopyranoso<2,1-d>oxazole

Chemical Property of 3,4,6-tri-O-acetyl-2'<(2R)-2-benzyloxytridecyl>-1,2-dideoxy-5'6'-dyhydro-α-D-glucopyranoso<2,1-d>oxazole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,4,6-tri-O-acetyl-2'<(2R)-2-benzyloxytridecyl>-1,2-dideoxy-5'6'-dyhydro-α-D-glucopyranoso<2,1-d>oxazole

There total 1 articles about 3,4,6-tri-O-acetyl-2'<(2R)-2-benzyloxytridecyl>-1,2-dideoxy-5'6'-dyhydro-α-D-glucopyranoso<2,1-d>oxazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium acetate (127-09-3) + benzyl bromide (100-39-0) + 3,4,6-tri-O-acetyl-1,2-dideoxy-4'5'-dyhydro-2'<2R-2-hydroxytridecyl>-α-D-glucopyranoso<2,1-d>oxazole (79189-80-3,88904-29-4) → Benzyl acetate (140-11-4) + dibenzyl ether (103-50-4) + 3,4,6-tri-O-acetyl-2'<(2R)-2-benzyloxytridecyl>-1,2-dideoxy-5'6'-dyhydro-α-D-glucopyranoso<2,1-d>oxazole (96236-89-4) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

With acetic anhydride; silver(l) oxide; Yield given. Multistep reaction; 1.) benzene, 45 degC, 9 h; 2.) pyridine, 0 degC, 2h;

DOI:10.1039/P19850000057

Reference yield: 63.0%

3,4,6-tri-O-acetyl-2'<(2R)-2-benzyloxytridecyl>-1,2-dideoxy-5'6'-dyhydro-α-D-glucopyranoso<2,1-d>oxazole (96236-89-4) + allyl alcohol (107-18-6) → allyl 3,4,6-tri-O-acetyl-2-<(3R)-3-benzyloxytetradecanamido>-2-deoxy-β-D-glucopyranoside (96236-90-7)

Guidance literature:

With toluene-4-sulfonic acid; In dichloromethane; toluene; at 50 ℃;

DOI:10.1039/P19850000057

upstream raw materials:

sodium acetate

benzyl bromide

3,4,6-tri-O-acetyl-1,2-dideoxy-4'5'-dyhydro-2'<2R-2-hydroxytridecyl>-α-D-glucopyranoso<2,1-d>oxazole

Downstream raw materials:

allyl 3,4,6-tri-O-acetyl-2-<(3R)-3-benzyloxytetradecanamido>-2-deoxy-β-D-glucopyranoside