[PtMe(dimethylsulfoxide)(6-phenyl-2,2'-bipyridine(-1H))]

Base Information

Chemical Name:[PtMe(dimethylsulfoxide)(6-phenyl-2,2'-bipyridine(-1H))]
CAS No.:405555-54-6
Molecular Formula:CH₃*C₂H₆OS*C₁₆H₁₁N₂*Pt
Molecular Weight:519.527
Hs Code.:

Synonyms:[PtMe(dimethylsulfoxide)(6-phenyl-2,2'-bipyridine(-1H))]

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Chemical Property of [PtMe(dimethylsulfoxide)(6-phenyl-2,2'-bipyridine(-1H))]

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Technology Process of [PtMe(dimethylsulfoxide)(6-phenyl-2,2'-bipyridine(-1H))]

There total 2 articles about [PtMe(dimethylsulfoxide)(6-phenyl-2,2'-bipyridine(-1H))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 61633-06-5
6-phenyl-2,2'-bipyridine

: cis-[Pt(DMSO)2(Me)2]

: 405555-54-6
[PtMe(dimethylsulfoxide)(6-phenyl-2,2'-bipyridine(-1H))]

Guidance literature:: In toluene; under Ar atm. to suspn. cis-(Pt(Me)2(DMSO)2) in toluene bipyridine was added and heated at 80°C for 2 h; soln. was evapd. to dryness, residue was dissolved in CH2Cl2, filtered and treated with pentane, ppt. was filtered, washed with pentane, and vac.-dried; elem. anal.;
DOI:10.1021/om0301583

Reference yield: 93.0%

: 70423-98-2
cis-dimethylbis[(sulfinyl-κS)bis[methane]]platinum(II)

: 61633-06-5
6-phenyl-2,2'-bipyridine

: 405555-54-6
(CH₃)Pt(NC₅H₄NC₅H₂C₆H₅)((CH₃)2SO)

Guidance literature:: In toluene; byproducts: methane; under Ar; suspn. of ligand and Pt complex (molar ratio 1:1) in toluene stirred at 90°C for 2 h; cooled to room temp.; evapd. to dryness; dissolved in CH2Cl2; filtered over Celite; concd.; treated with Et2O; filtered; ppt. washed with Et2O;
DOI:10.1021/om010913h

Reference yield: 76.0%

: 75-09-2
dichloromethane

: 405555-54-6
[PtMe(dimethylsulfoxide)(6-phenyl-2,2'-bipyridine(-1H))]

: 603-35-0
triphenylphosphine

: (Pt(CH₃)(NC₅H₄NC₅H₂C₆H₅)(P(C₆H₅)3))*0.5CH₂Cl₂

Guidance literature:: In dichloromethane; under Ar atm to soln. Pt complex in CH2Cl2 PPh3 was added and stirred for 4 h; soln. was concd., hexane was added, ppt. was filtered, washed with hexane, and vac.-dried; elem. anal.;
DOI:10.1021/om0301583