1H-Indene, 6-bromo-

Base Information

• Chemical Name: 1H-Indene, 6-bromo-
• CAS No.: 33065-61-1
• Molecular Formula: C9H7 Br
• Molecular Weight: 195.059
• Hs Code.: 2903999090
• Mol file: 33065-61-1.mol

Synonyms:Indene,6-bromo- (8CI); 6-Bromo-1H-indene; 6-Bromoindene

Chemical Property of 1H-Indene, 6-bromo-

Chemical Property:

• Boiling Point: 245℃
• Flash Point: 106℃
• PSA: 0.00000
• Density: 1.523
• LogP: 3.01840
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

98% ^*data from raw suppliers

6-bromo-1H-indene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1H-Indene, 6-bromo-

There total 9 articles about 1H-Indene, 6-bromo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

5-Bromo-1-indanone (34598-49-7) → 6-bromo-1H-indene (33065-61-1) + 5-bromo-1H-indene (75476-78-7)

Guidance literature:

5-Bromo-1-indanone; With lithium aluminium tetrahydride; at 0 ℃; for 2h;

With toluene-4-sulfonic acid; In benzene; at 75 ℃; for 2h;

DOI:10.1016/j.tetlet.2004.12.101

Reference yield:

ethanol (64-17-5) + 5-bromoindan-2-yl benzenesulfonate → 6-bromo-1H-indene (33065-61-1) + 5-Bromo-2-ethoxy-indan + benzenesulfonic acid (98-11-3)

Guidance literature:

With water; at 45 ℃; Rate constant; var. conc. of EtOH;

Reference yield:

methanol (67-56-1) + 5-bromoindan-2-yl benzenesulfonate → 6-bromo-1H-indene (33065-61-1) + 5-bromo-2-methoxy-2,3-dihydro-1H-indene + benzenesulfonic acid (98-11-3)

Guidance literature:

at 45 ℃; Rate constant; Kinetics; Thermodynamic data; ΔH(excit.), ΔS(excit.); var. temp.; also in the aq. MeOH;

upstream raw materials:

methanol

ethanol

5-Bromo-1-indanone

Downstream raw materials:

6-ethylisoquinoline

Refernces

• 1、 Lee, Ikchoon,Lee, Young Sook,Lee, Bon-Su,Lee, Hai Whang. "Solvolysis Mechanism of Indan-2-yl Arenesulfonates". . p. 1441 - 1445. Retrieved 2007/10/02.