methylphenylgermanium dichloride

Base Information

• Chemical Name: methylphenylgermanium dichloride
• CAS No.: 25179-00-4
• Molecular Formula: C₇H₈Cl₂Ge
• Molecular Weight: 235.637
• Mol file: 25179-00-4.mol

Synonyms:methylphenylgermanium dichloride

Chemical Property of methylphenylgermanium dichloride

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of methylphenylgermanium dichloride

There total 13 articles about methylphenylgermanium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

tetrachloromethane (56-23-5) + poly(methylphenylgermylene) (53572-89-7) → methylphenylgermanium dichloride (25179-00-4)

Guidance literature:

In cyclohexane; byproducts: CCl3CCl3; Irradiation (UV/VIS); photolysis of Ge-compd. in cyclohexane in the presence of CCl4 at 245 nm at room temp. for 30 min with a 110 W low pressure Hg arc lamp; Kinetics;

DOI:10.1021/om00014a002

Reference yield: 35.9%

Methyltrichlorosilane (75-79-6) + dimethyldiphenylgermane (7301-42-0) → germaniumtetrachloride (10038-98-9) + phenyldimethylchlorogermane (22702-76-7) + methylphenylgermanium dichloride (25179-00-4) + trichlorophenylgermane (1074-29-9)

Guidance literature:

aluminium trichloride; In solid; Si-compound reacted with (CH3)2Ge(C6H5)2 at 110-120°C for 3 h in presence of AlCl3;

DOI:10.1134/S1070363206100100

Reference yield: 21.6%

tetrachlorosilane (10026-04-7,53609-55-5) + dimethyldiphenylgermane (7301-42-0) → germaniumtetrachloride (10038-98-9) + phenyldimethylchlorogermane (22702-76-7) + methylphenylgermanium dichloride (25179-00-4) + trichlorophenylgermane (1074-29-9)

Guidance literature:

aluminium trichloride; In solid; Si-compound reacted with (CH3)2Ge(C6H5)2 at 110-120°C for 3 h in presence of AlCl3;

DOI:10.1134/S1070363206100100

upstream raw materials:

dimethylsilicon dichloride

chloro-trimethyl-silane

dimethyldiphenylgermane

tetrachlorosilane

Downstream raw materials:

29-methyl-29-phenyl-13,14,27,28,30,31-hexaoxa-29-germadispiro[11.2.11.5]hentriacontane

(C₆H₅)3Ge(Ge(C₆H₅)CH₃)Ge(C₆H₅)3

(OCH₃)benzodiselena(GeCH₃Ph)

benzodiselena(GeCH₃Ph)

Refernces

• 1、 Terent'ev,Platonov,Krylova,Egorov,Nikishin. "First synthesis of cyclic organogermanium peroxides, 1,2,4,5,7,8-hexaoxa-3-germonanes". . p. 1786 - 1788. Retrieved 2009/08/15.
• 2、 Mochida, Kunio,Yoneda, Isao,Wakasa, Masanobu. "Photochemistry of aryl-substituted trigermanes. Generation and mechanism of formation of germylenes". . p. 53 - 62. Retrieved 2007/10/02.