1,1 bis(di-isopropylphosphine)ferrocene palladium dichloride

Base Information

• Chemical Name: 1,1 bis(di-isopropylphosphine)ferrocene palladium dichloride
• CAS No.: 215788-65-1
• Molecular Formula: C22H36 Cl2 Fe P2 Pd
• Molecular Weight: 595.648
• Mol file: 215788-65-1.mol

Synonyms:(1,1'-Bis(diisopropylphosphino)ferrocene)dichloropalladium;Dichloro(1,1'-bis(diisopropylphosphino)ferrocene)palladium;Dichloro[Ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II)

Chemical Property of 1,1 bis(di-isopropylphosphine)ferrocene palladium dichloride

Chemical Property:

• Melting Point: 282-287 °C
• PSA: 27.18000
• LogP: 1.89170
• Storage Temp.: ?20°C

Purity/Quality:

98%,Pd>17.5% ^*data from raw suppliers

Dichloro[1,1'-bis(di-i-propylphosphino)ferrocene]palladium(II), 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 1,1 bis(di-isopropylphosphine)ferrocene palladium dichloride

There total 1 articles about 1,1 bis(di-isopropylphosphine)ferrocene palladium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

1,1'-bis(diisopropylphosphino)ferrocene (97239-80-0) + palladium dichloride → dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II) (215788-65-1)

Guidance literature:

With HCl; In diethyl ether; ethanol; PdCl2 suspn. in EtOH treated with conc. HCl, stirred at 50°C for30 min, filtered, Fe complex (1 equiv.) soln. in Et2O added at 20°C, stirred for 10 min; crystd. at -35°C, filtered, washed (H2O), dried (vac.); elem. anal.;

DOI:10.1016/S0022-328X(99)00670-1

Reference yield: 68.0%

dichloromethane (75-09-2) + dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II) (215788-65-1) + thiophenol (108-98-5) → [ferrocene-1,1'-diylbis(diisopropylphosphine-P)]bis(phenylthio)palladium(II)*CH2Cl2

Guidance literature:

With Et₃N; In toluene; byproducts: Et3NHCl; under N2, Pd-complex was added to toluene soln. of thiophenol; Et3NHCl was filtered off, filtrate was evapd. to dryness, residue was recrystd. from CH2Cl2/hexane (1:2), hexane was layered onto CH2Cl2 soln., slow diffusion of hexane at 258 K; elem. anal.;

DOI:10.1107/S0108270100000172

Reference yield: 49.0%

3,6-dichlorobenzene-1,2-dithiol (87314-49-6) + dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II) (215788-65-1) → [1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,6-dichloro-1,2-benzenedithiolate (403609-50-7)

Guidance literature:

With triethylamine; In dichloromethane; byproducts: (C2H5)3NHCl; (N2), mixed, stirred at room temp. for 3 h; filtered, pptd.(hexane), recrystd.(CH2Cl2/hexane), elem. anal., IR, NMR,MAS, XRD;

DOI:10.1016/S0277-5387(01)00923-8

upstream raw materials:

1,1'-bis(diisopropylphosphino)ferrocene

Downstream raw materials:

[1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,6-dichloro-1,2-benzenedithiolate

[Pd(H₂O)(1,1'-bis(diisopropylphosphino)ferrocene)(tosylato)](tosylate)

Refernces