METHYL LAURATE

Base Information

• Chemical Name: METHYL LAURATE
• CAS No.: 29972-79-0
• Molecular Formula: C13H24 O2
• Molecular Weight: 212.332
• Mol file: 29972-79-0.mol

Synonyms:Methyl11-dodecenoate

Chemical Property of METHYL LAURATE

Chemical Property:

• Melting Point: 4-5 °C(lit.)
• Refractive Index: n20/D 1.432
• Boiling Point: 262 °C766 mm Hg(lit.)
• Flash Point: >230 °F
• PSA: 26.30000
• Density: 0.87 g/mL at 25 °C(lit.)
• LogP: 3.85630
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

11-CIS-DODECENOIC ACID METHYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Intermediate for detergents, emulsifiers, wet-ting agents, stabilizers, lubricants, plasticizers, tex-tiles, flavoring.

Technology Process of METHYL LAURATE

There total 6 articles about METHYL LAURATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl cis-13-docosenoate (1120-34-9) → nonan-1-al (124-19-6) + oct-1-ene (111-66-0,25068-25-1) + methyl 11-dodecenoate (29972-79-0)

Guidance literature:

Multistep reaction;

DOI:10.1016/S0040-4020(01)96613-X

Reference yield:

methanol (67-56-1) + Elaidic Acid (112-79-8) + 9,12-octadecadienoic acid (60-33-3,506-21-8,2197-37-7,2420-42-0,2420-55-5,116745-32-5,26085-09-6,64080-88-2,7049-66-3,949900-18-9,60476-23-5,6144-28-1,67922-65-0,89718-18-3) + 1-hexadecylcarboxylic acid (57-10-3) + stearic acid (57-11-4) + 9,12,15-octadecatrienoic acid (463-40-1,1955-33-5,21661-10-9,21661-09-6,21661-13-2,21661-11-0) → octadec-9-enoic acid methyl ester (112-62-9) + methyl 11-dodecenoate (29972-79-0) + hexadecanoic acid methyl ester (112-39-0) + Methyl stearate (112-61-8) + methyl arachidate (1120-28-1) + dodec-3-ene (2030-83-3) + methyl 9-pentadecenoate (25915-47-3) + 1,19-nonadec-9-enedioic acid dimethyl ester (57568-16-8) + C22H40O4 (62402-77-1) + 1,21-heneicos-9-endioic dimethyl ester (1152412-76-4) + 6-pentadecene (42714-72-7) + 5-tridecene + 9-octadecene (5557-31-3) + dimethyl 9-octadecen-1,18-dioate (13481-97-5) + 9-eicosenoic acid methyl ester

Guidance literature:

Elaidic Acid; 9,12-octadecadienoic acid; 1-hexadecylcarboxylic acid; stearic acid; 9,12,15-octadecatrienoic acid; dichloro(tricyclohexylphosphino)(benzylidene)(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)ruthenium(III); at 53 ℃; for 20h; Neat (no solvent);

With ethyl vinyl ether;

methanol; sulfuric acid; Product distribution / selectivity;

Reference yield:

methanol (67-56-1) + Elaidic Acid (112-79-8) + 9,12-octadecadienoic acid (60-33-3,506-21-8,2197-37-7,2420-42-0,2420-55-5,116745-32-5,26085-09-6,64080-88-2,7049-66-3,949900-18-9,60476-23-5,6144-28-1,67922-65-0,89718-18-3) + 9-hexadecenoic acid (373-49-9,2091-29-4) + Arachidic acid (506-30-9) + 1-hexadecylcarboxylic acid (57-10-3) + stearic acid (57-11-4) → octadec-9-enoic acid methyl ester (112-62-9) + methyl 11-dodecenoate (29972-79-0) + hexadecanoic acid methyl ester (112-39-0) + Methyl stearate (112-61-8) + methyl arachidate (1120-28-1) + dodec-3-ene (2030-83-3) + methyl 9-pentadecenoate (25915-47-3) + 1,19-nonadec-9-enedioic acid dimethyl ester (57568-16-8) + C22H40O4 (62402-77-1) + 1,21-heneicos-9-endioic dimethyl ester (1152412-76-4) + 6-pentadecene (42714-72-7) + 5-tridecene + dimethyl 9-octadecen-1,18-dioate (13481-97-5) + 9-eicosenoic acid methyl ester

Guidance literature:

Elaidic Acid; 9,12-octadecadienoic acid; 9-hexadecenoic acid; Arachidic acid; 1-hexadecylcarboxylic acid; stearic acid; dichloro(tricyclohexylphosphino)(benzylidene)(1,3-dimesityl-4,5-dihydroimidazol-2-ylidene)ruthenium(III); at 50 - 53 ℃; for 20 - 72h; Neat (no solvent);

With ethyl vinyl ether;

methanol; sulfuric acid; Product distribution / selectivity;

upstream raw materials:

methyl cis-13-docosenoate

methanol

Elaidic Acid

9,12-octadecadienoic acid

Downstream raw materials:

(Z)-11-tetradecenyl acetate

(E)-tetradec-11-en-1-yl acetate

(Z)-11-hexadecen-1-yl acetate

methyl n-dodecanoate

Refernces

• 1、 Cardinale, G.,Laan, J. A. M.,Ward, J. P.. "PREPARATION OF TERMINAL ALKENIC ESTERS BY AN OXIDATIVE RADICAL REACTION". . p. 2899 - 2902. Retrieved 2007/10/02.