(C₅H₅)Fe(CO)2Mn(CO)4(P(OC₆H₅)3)

Base Information

• Chemical Name: (C₅H₅)Fe(CO)2Mn(CO)4(P(OC₆H₅)3)
• CAS No.: 108563-04-8
• Molecular Formula: C₂₉H₂₀FeMnO₉P
• Molecular Weight: 654.231
• Mol file: 108563-04-8.mol

Synonyms:(C₅H₅)Fe(CO)2Mn(CO)4(P(OC₆H₅)3)

Chemical Property of (C₅H₅)Fe(CO)2Mn(CO)4(P(OC₆H₅)3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₅H₅)Fe(CO)2Mn(CO)4(P(OC₆H₅)3)

There total 5 articles about (C₅H₅)Fe(CO)2Mn(CO)4(P(OC₆H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenyl phosphite (101-02-0) + (C5H5)FeMn(CO)6 (108563-07-1) → dicarbonyl(cyclopentadienyl)iron(II) chloride (12107-04-9) + pentacarbonylchloromanganese(I) (14100-30-2) + (C5H5)Fe(CO)2Mn(CO)4(P(OC6H5)3) (108563-04-8)

Guidance literature:

With tetrachloromethane; In methyl cyclohexane; Irradiation (UV/VIS); generation of (C5H5)FeMn(CO)6 by UV-irradiation at 93K in methylcyclohexane glass, thermal react. in presence of a 10fold excess of PR3 on warming up and annealing in presence of CCl4;; detn. by IR and UV;;

DOI:10.1021/ja00249a017

Reference yield:

triphenyl phosphite (101-02-0) + tetrachloromethane (56-23-5) + heptacarbonyl(η5-cyclopentadienyl)ironmanganese(Fe-Mn) → dicarbonyl(cyclopentadienyl)iron(II) chloride (12107-04-9) + pentacarbonylchloromanganese(I) (14100-30-2) + Mn(CO)4(P(O(C6H5))3)Cl (85362-16-9) + (C5H5)Fe(CO)2Mn(CO)4(P(OC6H5)3) (108563-04-8)

Guidance literature:

In tetrachloromethane; Irradiation (UV/VIS); 313nm and 336nm, 1E-4M soln. of complex compound in CCl4 with 1E-3M P(OC6H5)3; determination of quantum yield;;

DOI:10.1021/ja00249a017

Reference yield:

triphenyl phosphite (101-02-0) + (C5H5)FeMn(CO)6 (108563-07-1) → (C5H5)Fe(CO)2Mn(CO)4(P(OC6H5)3) (108563-04-8)

Guidance literature:

In methyl cyclohexane; Irradiation (UV/VIS); generation of (C5H5)FeMn(CO)6 by UV-irradiation at 93K in methylcyclohexane glass, thermal react. in presence of a 10fold excess of PR3 on warming up and annealing (also in presence of CCl4);; detn. by IR and UV;;

DOI:10.1021/ja00249a017

upstream raw materials:

triphenyl phosphite

tetrachloromethane

dimanganese decacarbonyl

(C₅H₅)FeMn(CO)6

Downstream raw materials:

dicarbonyl(cyclopentadienyl)iron(II) chloride

Mn(CO)4(P(O(C₆H₅))3)Cl