(4S,6S)-4-[2-(benzyloxy)ethyl]-2,2-dimethyl-6-(prop-2-en-1-yl)-1,3-dioxane

Base Information

Chemical Name:(4S,6S)-4-[2-(benzyloxy)ethyl]-2,2-dimethyl-6-(prop-2-en-1-yl)-1,3-dioxane
CAS No.:853923-24-7
Molecular Formula:C₁₈H₂₆O₃
Molecular Weight:290.403
Hs Code.:

Synonyms:(4S,6S)-4-[2-(benzyloxy)ethyl]-2,2-dimethyl-6-(prop-2-en-1-yl)-1,3-dioxane

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Chemical Property of (4S,6S)-4-[2-(benzyloxy)ethyl]-2,2-dimethyl-6-(prop-2-en-1-yl)-1,3-dioxane

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Technology Process of (4S,6S)-4-[2-(benzyloxy)ethyl]-2,2-dimethyl-6-(prop-2-en-1-yl)-1,3-dioxane

There total 8 articles about (4S,6S)-4-[2-(benzyloxy)ethyl]-2,2-dimethyl-6-(prop-2-en-1-yl)-1,3-dioxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 853923-30-5
(3R,5S)-1-(benzyloxy)oct-7-ene-3,5-diol

: 77-76-9
2,2-dimethoxy-propane

: 853923-24-7
(4S,6S)-4-[2-(benzyloxy)ethyl]-2,2-dimethyl-6-(prop-2-en-1-yl)-1,3-dioxane

Guidance literature:: With toluene-4-sulfonic acid; In dimethyl sulfoxide;
DOI:10.1016/j.tetlet.2005.03.202

Reference yield:

: 853923-29-2
(R)-8-Benzyloxy-6-hydroxy-oct-1-en-4-one

: 853923-24-7
(4S,6S)-4-[2-(benzyloxy)ethyl]-2,2-dimethyl-6-(prop-2-en-1-yl)-1,3-dioxane

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / BEt₂OMe; NaBH₄ / tetrahydrofuran

2: 94 percent / PTSA / dimethylsulfoxide

With sodium tetrahydroborate; diethyl methoxy borane; toluene-4-sulfonic acid; In tetrahydrofuran; dimethyl sulfoxide;
DOI:10.1016/j.tetlet.2005.03.202

Reference yield:

: 124010-06-6
(R)-(+)-5-(benzyloxy)-3-(tert-butyldimethylsilyloxy)pentanal

: 853923-24-7
(4S,6S)-4-[2-(benzyloxy)ethyl]-2,2-dimethyl-6-(prop-2-en-1-yl)-1,3-dioxane

Guidance literature:: Multi-step reaction with 5 steps

1: 82 percent / Zn; NH₄Cl / tetrahydrofuran / 20 °C

2: 72 percent / PCC; NaOAc / CH₂Cl₂ / 20 °C

3: 63 percent / HF*pyridine / tetrahydrofuran / 20 °C

4: 75 percent / BEt₂OMe; NaBH₄ / tetrahydrofuran

5: 94 percent / PTSA / dimethylsulfoxide

With sodium tetrahydroborate; diethyl methoxy borane; sodium acetate; ammonium chloride; toluene-4-sulfonic acid; pyridine hydrogenfluoride; pyridinium chlorochromate; zinc; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide;
DOI:10.1016/j.tetlet.2005.03.202