[(pentamethylcyclopentadienyl)Ru{PhP(C₆H₄-o-S)₂}]

Base Information

Chemical Name:[(pentamethylcyclopentadienyl)Ru{PhP(C₆H₄-o-S)₂}]
CAS No.:1254784-42-3
Molecular Formula:C₂₈H₂₈PRuS₂
Molecular Weight:560.706
Hs Code.:

[(pentamethylcyclopentadienyl)Ru{PhP(C<sub>6</sub>H<sub>4</sub>-o-S)<sub>2</sub>}]

Synonyms:[(pentamethylcyclopentadienyl)Ru{PhP(C₆H₄-o-S)₂}]

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Chemical Property of [(pentamethylcyclopentadienyl)Ru{PhP(C₆H₄-o-S)₂}]

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Technology Process of [(pentamethylcyclopentadienyl)Ru{PhP(C₆H₄-o-S)₂}]

There total 1 articles about [(pentamethylcyclopentadienyl)Ru{PhP(C₆H₄-o-S)₂}] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)]

: 119327-18-3
bis(phenyl-2-thiol)phenylphosphine

: 1254784-42-3
[(pentamethylcyclopentadienyl)Ru{PhP(C₆H₄-o-S)₂}]

Guidance literature:: With C₄H₉Li; In tetrahydrofuran; hexane; (inert atm., Schlenk technique); addn. of hexane soln. of butyllithium to THF soln. of dithiol deriv. at 0°C, keeping for 15 min, addn. to THF suspn. of ruthenium compd. at room temp., stirring at room temp. for 18 h; evapn., recrystn. (CH2Cl2/hexane), elem. anal.;
DOI:10.1021/om100852x

Reference yield: 88.0%

: bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)]

: 75-09-2
dichloromethane

: 1254784-42-3
[(pentamethylcyclopentadienyl)Ru{PhP(C₆H₄-o-S)₂}]

: 1255070-52-0
[(C₅Me₅)2Ru₂Cl(PhP(C₆H₄-o-S)2)]Cl*dichloromethane

Guidance literature:: In dichloromethane; (inert atm., Schlenk technique); stirring mixt. of ruthenium compds. at room temp. for 20 h; evapn., washing with THF, recrystn. (CH2Cl2/hexane), NMR;
DOI:10.1021/om100852x

Reference yield: 83.0%

: bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)]

: 75-09-2
dichloromethane

: 1254784-42-3
[(pentamethylcyclopentadienyl)Ru{PhP(C₆H₄-o-S)₂}]

: 2923-28-6
silver trifluoromethanesulfonate

: [(pentamethylcyclopentadienyl)Ru{PhP(C₆H₄-o-S)₂}Ru(pentamethylcyclopentadienyl)](OTf)₂_*0.5CH₂Cl₂

Guidance literature:: In dichloromethane; (inert atm., Schlenk technique); stirring mixt. of ruthenium compds. at room temp. for 20 h, addn. of silver compd., stirring at room temp. for 1 h; filtration, concg., recrystn. (ethanol/ether), recrystn. (CH2Cl2/hexane), elem. anal.;
DOI:10.1021/om100852x