3,4,6-tri-O-benzyl-β-D-glucopyranosyl 1-diethyldithiocarbamate

Base Information

• Chemical Name: 3,4,6-tri-O-benzyl-β-D-glucopyranosyl 1-diethyldithiocarbamate
• CAS No.: 1380516-32-4
• Molecular Formula: C₃₂H₃₉NO₅S₂
• Molecular Weight: 581.797
• Mol file: 1380516-32-4.mol

Synonyms:3,4,6-tri-O-benzyl-β-D-glucopyranosyl 1-diethyldithiocarbamate

Chemical Property of 3,4,6-tri-O-benzyl-β-D-glucopyranosyl 1-diethyldithiocarbamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,4,6-tri-O-benzyl-β-D-glucopyranosyl 1-diethyldithiocarbamate

There total 1 articles about 3,4,6-tri-O-benzyl-β-D-glucopyranosyl 1-diethyldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diethylammonium diethyldithiocarbamate (1518-58-7) + glucal epoxide (1011723-04-8) → 3,4,6-tri-O-benzyl-β-D-glucopyranosyl 1-diethyldithiocarbamate (1380516-32-4)

Guidance literature:

In tetrahydrofuran; methanol; at 0 - 20 ℃; for 2.5h;

DOI:10.1021/ol301349w

Reference yield: 83.0%

triethylsilyl chloride (994-30-9) + 3,4,6-tri-O-benzyl-β-D-glucopyranosyl 1-diethyldithiocarbamate (1380516-32-4) → 3,4,6-tri-O-benzyl-2-O-triethylsilyl-β-D-glucopyranosyl 1-diethyldithiocarbamate (1563178-09-5)

Guidance literature:

With 1H-imidazole; In tetrahydrofuran; at 0 - 20 ℃; for 12h; Inert atmosphere;

DOI:10.1021/jo500032k

Reference yield: 82.0%

3,4,6-tri-O-benzyl-β-D-glucopyranosyl 1-diethyldithiocarbamate (1380516-32-4) + benzyl bromide (100-39-0) → 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl 1-diethyldithiocarbamate (116556-69-5)

Guidance literature:

With sodium hexamethyldisilazane; In N,N-dimethyl-formamide; toluene; at -50 - 20 ℃; for 2.08333h; Inert atmosphere;

DOI:10.1021/jo500032k

upstream raw materials:

diethylammonium diethyldithiocarbamate

glucal epoxide

Downstream raw materials:

3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->3)-4,6-O-benzylidene-D-glucal

O-(3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1<*>3)-1,5-anhydro-4,6-O-benzylidene-2-deoxy-D-arabino-hex-1-enitol

O-(3,4,6-Tri-O-benzyl-β-D-glucopyranosyl)-(1->6)-1,5-anhydro-3,4-di-O-benzyl-2-deoxy-D-arabino-hex-1-enopyranose

C₂₆H₂₆O₇